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Nitrogen cation


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Nitrogen cation + Argon = (Nitrogen cation bullet Argon)

By formula: N2+ + Ar = (N2+ bullet Ar)

Quantity Value Units Method Reference Comment
Deltar112.kJ/molPD/KERDKim and Bowers, 1990gas phase; switching reaction(N2+)N2; Hiraoka and Nakajima, 1988
Deltar106.kJ/molPHPMSTeng and Conway, 1973gas phase; switching reaction(N2+)N2
Quantity Value Units Method Reference Comment
Deltar81.6J/mol*KPD/KERDKim and Bowers, 1990gas phase; switching reaction(N2+)N2; Hiraoka and Nakajima, 1988
Deltar57.3J/mol*KPHPMSTeng and Conway, 1973gas phase; switching reaction(N2+)N2

(Nitrogen cation bullet Argon) + Argon = (Nitrogen cation bullet 2Argon)

By formula: (N2+ bullet Ar) + Ar = (N2+ bullet 2Ar)

Quantity Value Units Method Reference Comment
Deltar16.kJ/molPHPMSHiraoka, Mori, et al., 1992gas phase; «DELTA»rH>
Quantity Value Units Method Reference Comment
Deltar71.J/mol*KPHPMSHiraoka, Mori, et al., 1992gas phase; «DELTA»rH>

(Nitrogen cation bullet 2Argon) + Argon = (Nitrogen cation bullet 3Argon)

By formula: (N2+ bullet 2Ar) + Ar = (N2+ bullet 3Ar)

Quantity Value Units Method Reference Comment
Deltar7.3 ± 0.8kJ/molPHPMSHiraoka, Mori, et al., 1992gas phase
Quantity Value Units Method Reference Comment
Deltar57.3J/mol*KPHPMSHiraoka, Mori, et al., 1992gas phase

(Nitrogen cation bullet 3Argon) + Argon = (Nitrogen cation bullet 4Argon)

By formula: (N2+ bullet 3Ar) + Ar = (N2+ bullet 4Ar)

Quantity Value Units Method Reference Comment
Deltar7.0 ± 0.8kJ/molPHPMSHiraoka, Mori, et al., 1992gas phase
Quantity Value Units Method Reference Comment
Deltar74.9J/mol*KPHPMSHiraoka, Mori, et al., 1992gas phase

(Nitrogen cation bullet 4Argon) + Argon = (Nitrogen cation bullet 5Argon)

By formula: (N2+ bullet 4Ar) + Ar = (N2+ bullet 5Ar)

Quantity Value Units Method Reference Comment
Deltar6.6 ± 0.8kJ/molPHPMSHiraoka, Mori, et al., 1992gas phase
Quantity Value Units Method Reference Comment
Deltar71.1J/mol*KPHPMSHiraoka, Mori, et al., 1992gas phase

(Nitrogen cation bullet 5Argon) + Argon = (Nitrogen cation bullet 6Argon)

By formula: (N2+ bullet 5Ar) + Ar = (N2+ bullet 6Ar)

Quantity Value Units Method Reference Comment
Deltar6.5 ± 0.8kJ/molPHPMSHiraoka, Mori, et al., 1992gas phase
Quantity Value Units Method Reference Comment
Deltar72.8J/mol*KPHPMSHiraoka, Mori, et al., 1992gas phase

(Nitrogen cation bullet 6Argon) + Argon = (Nitrogen cation bullet 7Argon)

By formula: (N2+ bullet 6Ar) + Ar = (N2+ bullet 7Ar)

Quantity Value Units Method Reference Comment
Deltar6.4 ± 0.8kJ/molPHPMSHiraoka, Mori, et al., 1992gas phase
Quantity Value Units Method Reference Comment
Deltar72.4J/mol*KPHPMSHiraoka, Mori, et al., 1992gas phase

(Nitrogen cation bullet 7Argon) + Argon = (Nitrogen cation bullet 8Argon)

By formula: (N2+ bullet 7Ar) + Ar = (N2+ bullet 8Ar)

Quantity Value Units Method Reference Comment
Deltar6.40kJ/molPHPMSHiraoka, Mori, et al., 1992gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar71.J/mol*KN/AHiraoka, Mori, et al., 1992gas phase; Entropy change calculated or estimated

(Nitrogen cation bullet 8Argon) + Argon = (Nitrogen cation bullet 9Argon)

By formula: (N2+ bullet 8Ar) + Ar = (N2+ bullet 9Ar)

Quantity Value Units Method Reference Comment
Deltar6.36kJ/molPHPMSHiraoka, Mori, et al., 1992gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar71.J/mol*KN/AHiraoka, Mori, et al., 1992gas phase; Entropy change calculated or estimated

Nitrogen cation + helium = (Nitrogen cation bullet helium)

By formula: N2+ + He = (N2+ bullet He)

Quantity Value Units Method Reference Comment
Deltar2.kJ/molPDissBieske, Soliva, et al., 1990gas phase; same «DELTA»rH for N2+(B) and (N2+)X; ab initio, Miller, Tennyson, et al., 1988

Nitrogen cation + Nitrogen = (Nitrogen cation bullet Nitrogen)

By formula: N2+ + N2 = (N2+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar102. - 102.kJ/molRNGN/ARange of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar87.9J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase
Deltar67.8J/mol*KPHPMSTeng and Conway, 1973gas phase
Deltar81.6J/mol*KPHPMSPayzant and Kebarle, 1970gas phase
Deltar46.J/mol*KDTVarney, 1968gas phase; Entropy change is questionable
Deltar-4.J/mol*KDTVarney, 1959gas phase; Entropy change is questionable

(Nitrogen cation bullet Nitrogen) + Nitrogen = (Nitrogen cation bullet 2Nitrogen)

By formula: (N2+ bullet N2) + N2 = (N2+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar11.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Deltar5.9kJ/molPILinn, Ono, et al., 1981gas phase
Quantity Value Units Method Reference Comment
Deltar62.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation bullet 2Nitrogen) + Nitrogen = (Nitrogen cation bullet 3Nitrogen)

By formula: (N2+ bullet 2N2) + N2 = (N2+ bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar11.3 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar66.1J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation bullet 3Nitrogen) + Nitrogen = (Nitrogen cation bullet 4Nitrogen)

By formula: (N2+ bullet 3N2) + N2 = (N2+ bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar10.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar69.5J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation bullet 4Nitrogen) + Nitrogen = (Nitrogen cation bullet 5Nitrogen)

By formula: (N2+ bullet 4N2) + N2 = (N2+ bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar10.3 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar85.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation bullet 5Nitrogen) + Nitrogen = (Nitrogen cation bullet 6Nitrogen)

By formula: (N2+ bullet 5N2) + N2 = (N2+ bullet 6N2)

Quantity Value Units Method Reference Comment
Deltar9.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar90.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation bullet 6Nitrogen) + Nitrogen = (Nitrogen cation bullet 7Nitrogen)

By formula: (N2+ bullet 6N2) + N2 = (N2+ bullet 7N2)

Quantity Value Units Method Reference Comment
Deltar8.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar85.4J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation bullet 7Nitrogen) + Nitrogen = (Nitrogen cation bullet 8Nitrogen)

By formula: (N2+ bullet 7N2) + N2 = (N2+ bullet 8N2)

Quantity Value Units Method Reference Comment
Deltar7.8 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar80.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation bullet 8Nitrogen) + Nitrogen = (Nitrogen cation bullet 9Nitrogen)

By formula: (N2+ bullet 8N2) + N2 = (N2+ bullet 9N2)

Quantity Value Units Method Reference Comment
Deltar7.4 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar81.6J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation bullet 9Nitrogen) + Nitrogen = (Nitrogen cation bullet 10Nitrogen)

By formula: (N2+ bullet 9N2) + N2 = (N2+ bullet 10N2)

Quantity Value Units Method Reference Comment
Deltar7.4 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar86.6J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation bullet 10Nitrogen) + Nitrogen = (Nitrogen cation bullet 11Nitrogen)

By formula: (N2+ bullet 10N2) + N2 = (N2+ bullet 11N2)

Quantity Value Units Method Reference Comment
Deltar6.9 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar84.5J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kim and Bowers, 1990
Kim, H.S.; Bowers, M.T., Energetics, Structure and Photodissociation Dynamics of the Cluster Ar.N2+, J. Chem. Phys., 1990, 93, 2, 1158, https://doi.org/10.1063/1.459179 . [all data]

Hiraoka and Nakajima, 1988
Hiraoka, K.; Nakajima, G., A Determination of the Stabilities of N2+(N2)n and O2+(N2)n with n = 1 - 11 from Measurements of the Gas - Phase Ion Equilibria, J. Chem. Phys., 1988, 88, 12, 7709, https://doi.org/10.1063/1.454285 . [all data]

Teng and Conway, 1973
Teng, H.H.; Conway, D.C., Ion - Molecule Equilibria in Mixtures of N2 and Ar, J. Chem. Phys., 1973, 59, 5, 2316, https://doi.org/10.1063/1.1680338 . [all data]

Hiraoka, Mori, et al., 1992
Hiraoka, K.; Mori, T.; Yamabe, S., Gas-Phase Solvation of N2+ with Ar Atoms - A Charge Switch in the Reaction N2+(Ar)...Ar+(N2), Chem. Phys. Lett., 1992, 189, 1, 7, https://doi.org/10.1016/0009-2614(92)85144-Y . [all data]

Bieske, Soliva, et al., 1990
Bieske, E.J.; Soliva, A.; Welker, M.A.; Maier, J.P., The B<---X Electronic Spectrum of N2+ He, J. Chem. Phys., 1990, 93, 6, 4477, https://doi.org/10.1063/1.458732 . [all data]

Miller, Tennyson, et al., 1988
Miller, S.; Tennyson, J.; Follmeg, B.; Rosmus, P.; Werner, H., Ab initio Investigation of the Bond Rovibrational States in the Electronic Ground State of HeN2+, J. Chem. Phys., 1988, 89, 4, 2178, https://doi.org/10.1063/1.455062 . [all data]

Payzant and Kebarle, 1970
Payzant, J.D.; Kebarle, P., Clustering Equilibrium N2+ + 2N2 = N4+ + N2 and the Bond Dissociation Energy of N4+, J. Chem. Phys., 1970, 53, 12, 4723, https://doi.org/10.1063/1.1674010 . [all data]

Varney, 1968
Varney, R.N., Equilibrium Constant and Rates for the Reversible Reaction N4+ -> N2+ + N2, Phys. Rev., 1968, 174, 1, 165, https://doi.org/10.1103/PhysRev.174.165 . [all data]

Varney, 1959
Varney, R.N., Molecular Ions, J. Chem. Phys., 1959, 31, 5, 1314, https://doi.org/10.1063/1.1730590 . [all data]

Linn, Ono, et al., 1981
Linn, S.H.; Ono, Y.; Ng, C.Y., Molecular Beam Photoionization Study of CO, N2, and NO Dimers and Clusters, J. Chem. Phys., 1981, 74, 6, 3342, https://doi.org/10.1063/1.441486 . [all data]


Notes

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