Reaction data
+ 
= ( • )
Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 24.4 to 24.4 | kcal/mol | RNG | N/A | Range of 6 values; Individual data points |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 21.0 | cal/mol*K | PHPMS | Hiraoka and Nakajima, 1988 | gas phase |
| ΔrS° | 16.2 | cal/mol*K | PHPMS | Teng and Conway, 1973 | gas phase |
| ΔrS° | 19.5 | cal/mol*K | PHPMS | Payzant and Kebarle, 1970 | gas phase |
| ΔrS° | 11. | cal/mol*K | DT | Varney, 1968 | gas phase; Entropy change is questionable |
| ΔrS° | -1. | cal/mol*K | DT | Varney, 1959 | gas phase; Entropy change is questionable |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hiraoka and Nakajima, 1988
Hiraoka, K.; Nakajima, G.,
A Determination of the Stabilities of N2+(N2)n and O2+(N2)n with n = 1 - 11 from Measurements of the Gas - Phase Ion Equilibria,
J. Chem. Phys., 1988, 88, 12, 7709, https://doi.org/10.1063/1.454285
. [all data]
Teng and Conway, 1973
Teng, H.H.; Conway, D.C.,
Ion - Molecule Equilibria in Mixtures of N2 and Ar,
J. Chem. Phys., 1973, 59, 5, 2316, https://doi.org/10.1063/1.1680338
. [all data]
Payzant and Kebarle, 1970
Payzant, J.D.; Kebarle, P.,
Clustering Equilibrium N2+ + 2N2 = N4+ + N2 and the Bond Dissociation Energy of N4+,
J. Chem. Phys., 1970, 53, 12, 4723, https://doi.org/10.1063/1.1674010
. [all data]
Varney, 1968
Varney, R.N.,
Equilibrium Constant and Rates for the Reversible Reaction N4+ -> N2+ + N2,
Phys. Rev., 1968, 174, 1, 165, https://doi.org/10.1103/PhysRev.174.165
. [all data]
Varney, 1959
Varney, R.N.,
Molecular Ions,
J. Chem. Phys., 1959, 31, 5, 1314, https://doi.org/10.1063/1.1730590
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.