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Manganese, acetylpentacarbonyl-, (OC-6-21)-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

Manganese, pentacarbonylmethyl- (solution) + Carbon monoxide (solution) = Manganese, acetylpentacarbonyl-, (OC-6-21)- (solution)

By formula: C6H3MnO5 (solution) + CO (solution) = C7H3MnO6 (solution)

Quantity Value Units Method Reference Comment
Deltar-56.1 ± 4.2kJ/molRSCNolan, López de la Vega, et al., 1986solvent: Tetrahydrofuran
Deltar-52.7kJ/molEqSCalderazzo, 1977solvent: 2,2'-diethoxydiethyl ether

Manganese, acetylpentacarbonyl-, (OC-6-21)- (cr) + 1.5Bromine (g) = manganese dibromide (cr) + 6Carbon monoxide (g) + Methane, bromo- (g)

By formula: C7H3MnO6 (cr) + 1.5Br2 (g) = Br2Mn (cr) + 6CO (g) + CH3Br (g)

Quantity Value Units Method Reference Comment
Deltar-161. ± 5.kJ/molHAL-HFCConnor, Zafarani-Moattar, et al., 1982 

Manganese, acetylpentacarbonyl-, (OC-6-21)- (cr) = Manganese, pentacarbonylmethyl- (g) + Carbon monoxide (g)

By formula: C7H3MnO6 (cr) = C6H3MnO5 (g) + CO (g)

Quantity Value Units Method Reference Comment
Deltar119.3 ± 0.9kJ/molTD-HFCConnor, Zafarani-Moattar, et al., 1982 

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nolan, López de la Vega, et al., 1986
Nolan, S.P.; López de la Vega, R.; Hoff, C.D., J. Am. Chem. Soc., 1986, 108, 7852. [all data]

Calderazzo, 1977
Calderazzo, F., Angew. Chem. Int. Ed. Engl., 1977, 16, 299. [all data]

Connor, Zafarani-Moattar, et al., 1982
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; El-Saied, N.I.; Suradi, S.; Carson, R.; Al Takkhin, G.; Skinner, H.A., Organomet., 1982, 1, 1166. [all data]


Notes

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