Chromium monofluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to CrF+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
1.76 ± 0.40R-ABoltalina, Borshchevskii, et al., 1991Data at 0 K. See also Pramann and Rademann, 1999; value altered from reference due to conversion from electron convention to ion convention; B
1.0 ± 0.40EIAEFlesch, White, et al., 1969From CrO2F2; B

Ionization energy determinations

IE (eV) Method Reference Comment
9.3 ± 0.4EIMalkerova, Alikhanyan, et al., 1979LLK
8.4 ± 0.3EIKent and Margrave, 1965RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Boltalina, Borshchevskii, et al., 1991
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N., Thermochemistry of Chromium Gaseous Fluorides and Their Negative Ions, Zh. Fiz. Khim. SSSR, 1991, 65, 884. [all data]

Pramann and Rademann, 1999
Pramann, A.; Rademann, K., Mass-spectrometric study of formation and stability of manganese and manganese oxide cluster anions, Int. J. Mass Spectrom., 1999, 187, 673-683, https://doi.org/10.1016/S1387-3806(98)14197-0 . [all data]

Flesch, White, et al., 1969
Flesch, G.D.; White, R.M.; Svec, H.J., The Positive and Negative Ion Mass Spectra of Chromyl Chloride and Chromyl Fluoride, Int. J. Mass Spectrom. Ion Phys., 1969, 3, 5, 239, https://doi.org/10.1016/0020-7381(69)80079-3 . [all data]

Malkerova, Alikhanyan, et al., 1979
Malkerova, I.P.; Alikhanyan, A.S.; Pervov, V.S.; Tripol'skaya, T.A.; Gorgoraki, V.I.; Malyusov, V.A., High-temperature investigations of chromium lower fluorides, Russ. J. Inorg. Chem., 1979, 24, 1775. [all data]

Kent and Margrave, 1965
Kent, R.A.; Margrave, J.L., Mass spectrometric studies at high temperatures. VII. The sublimation pressure of chromium(II) fluoride and the dissociation energy of chromium(I) fluoride, J. Am. Chem. Soc., 1965, 87, 3582. [all data]


Notes

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