Selenium monohydride


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Se- + Hydrogen cation = Selenium monohydride

By formula: Se- + H+ = HSe

Quantity Value Units Method Reference Comment
Δr339.9 ± 1.1kcal/molD-EAVandevraye, Drag, et al., 2012gas phase; Given: 2.0206046(11) eV
Quantity Value Units Method Reference Comment
Δr333.9 ± 1.2kcal/molH-TSVandevraye, Drag, et al., 2012gas phase; Given: 2.0206046(11) eV

Constants of diatomic molecules

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through July, 1977

Symbols used in the table of constants
SymbolMeaning
State electronic state and / or symmetry symbol
Te minimum electronic energy (cm-1)
ωe vibrational constant – first term (cm-1)
ωexe vibrational constant – second term (cm-1)
ωeye vibrational constant – third term (cm-1)
Be rotational constant in equilibrium position (cm-1)
αe rotational constant – first term (cm-1)
γe rotation-vibration interaction constant (cm-1)
De centrifugal distortion constant (cm-1)
βe rotational constant – first term, centrifugal force (cm-1)
re internuclear distance (Å)
Trans. observed transition(s) corresponding to electronic state
ν00 position of 0-0 band (units noted in table)
Diatomic constants for (80)SeH
StateTeωeωexeωeyeBeαeγeDeβereTrans.ν00
F   1        F ← X1 71190
Donovan, Little, et al., 1972
E   2        E ← X1 69604
Donovan, Little, et al., 1972
D   3        D ← X1 66814
Donovan, Little, et al., 1972
C   4        C ← X1 R 55797 HQ
Donovan, Little, et al., 1972
StateTeωeωexeωeyeBeαeγeDeβereTrans.ν00
A (2Σ+) (31500) [1232] (H) (172) 5 6         
           A ← X1 R 31048 (H)
Lindgren, 1968
X2 2Π1/2 (1815) 7 (2400) 5   [7.78] 8     [1.475] 9  
Radford, 1964; Carrington, Currie, et al., 1970; Byfleet, Carrington, et al., 1971
X1 2Π3/2 0 (2400) 5   [7.78] 8     [1.475] 9  
Radford, 1964; Carrington, Currie, et al., 1970; Byfleet, Carrington, et al., 1971

Notes

1Weak diffuse band.
2Diffuse band.
3Strong diffuse band.
4Strong double-headed band.
5From isotope relations between SeH and SeD.
6Diffuse bands.
7From the photodetachment spectra of SeH- and SeD-.
8Λ-doubling frequencies Carrington, Currie, et al., 1970.
9ESR sp. 12
10Extrapolation of the vibrational levels in A 2Σ+ assuming dissociation of this state into 2S + 1D.
11From Rydberg assignments of Donovan, Little, et al., 1972; doubtful.
12μel = 0.49 D Byfleet, Carrington, et al., 1971. 77Se hf coupling Carrington, Currie, et al., 1970.
13μel = 0.483 D Byfleet, Carrington, et al., 1971. 77Se hf coupling Carrington, Currie, et al., 1970.

References

Go To: Top, Reaction thermochemistry data, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Vandevraye, Drag, et al., 2012
Vandevraye, M.; Drag, C.; Blondel, C., Electron affinity of selenium measured by photodetachment microscopy, Phys. Rev. A, 2012, 85, 1, 015401, https://doi.org/10.1103/PhysRevA.85.015401 . [all data]

Donovan, Little, et al., 1972
Donovan, R.J.; Little, D.J.; Konstantatos, J., Vacuum ultraviolet spectra of transient molecules and radicals, J. Chem. Soc. Faraday Trans. 2, 1972, 68, 1812. [all data]

Lindgren, 1968
Lindgren, B., Diffuse spectra of SeH and SeD, J. Mol. Spectrosc., 1968, 28, 536. [all data]

Radford, 1964
Radford, H.E., Synthesis of diatomic radicals, J. Chem. Phys., 1964, 40, 2732. [all data]

Carrington, Currie, et al., 1970
Carrington, A.; Currie, G.N.; Lucas, N.J.D., Electron resonance of gaseous diatomic hydrides. II. Rotational constant, Λ-doubling, hyperfine structure and dipole moment of SeH and SeD, Proc. R. Soc. London A, 1970, 315, 355. [all data]

Byfleet, Carrington, et al., 1971
Byfleet, C.R.; Carrington, A.; Russell, D.K., Electric dipole moments of open-shell diatomic molecules, Mol. Phys., 1971, 20, 271. [all data]


Notes

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