Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

HOClO


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Td = 25000 Ar Johnsson, Engdahl, et al., 1996

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

1 OH stretch 3556.7 Ne IR Yoshinobu, Akai, et al., 2009
1 OH stretch 3527.1 vs Ar IR Johnsson, Engdahl, et al., 1996
2 HOCl deform. 1173.2 Ne IR Yoshinobu, Akai, et al., 2009
2 HOCl deform. 1176.9 w m Ar IR Johnsson, Engdahl, et al., 1996
3 ClO stretch 978.3 Ne IR Yoshinobu, Akai, et al., 2009
3 ClO stretch 973.9 s Ar IR Johnsson, Engdahl, et al., 1996
4 OCl stretch 591.5 w m Ar IR Johnsson, Engdahl, et al., 1996

Additional references: Jacox, 1998, page 241

Notes

wWeak
mMedium
sStrong
vsVery strong
dPhotodissociation threshold

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Johnsson, Engdahl, et al., 1996
Johnsson, K.; Engdahl, A.; Nelander, B., IR and Photodecomposition Spectroscopic Study of HOClO and HClO, J. Phys. Chem., 1996, 100, 10, 3923, https://doi.org/10.1021/jp952868v . [all data]

Yoshinobu, Akai, et al., 2009
Yoshinobu, T.; Akai, N.; Kawai, A.; Shibuya, K., Neon matrix-isolation infrared spectrum of HOOCl measured upon the VUV-light irradiation of an HCl/O2 mixture, Chem. Phys. Lett., 2009, 477, 1-3, 70, https://doi.org/10.1016/j.cplett.2009.06.064 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References