Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Iodine monofluoride


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to FI+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)10.54 ± 0.01eVN/AN/AL

Electron affinity determinations

EA (eV) Method Reference Comment
>1.0 ± 0.19EIAEHeni and Illenberger, 1986From CF3I. Based on periodic trends, EA is likely to be ca. 2.0 eV; B
2.61382N/ACheck, Faust, et al., 2001FeCl4-(q); ; «DELTA»S(EA)=5.6; B

Ionization energy determinations

IE (eV) Method Reference Comment
10.54 ± 0.01PEColbourn, Dyke, et al., 1978LLK
10.5 ± 0.3EIIrsa and Friedman, 1958RDSH
10.62PEDyke, Josland, et al., 1984Vertical value; LBLHLM

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Heni and Illenberger, 1986
Heni, M.; Illenberger, E., Dissociative Electron Attachment to CF3I: An Example of a Completely Unbalanced Excess Energy Distribution, Chem. Phys. Lett., 1986, 131, 4-5, 314, https://doi.org/10.1016/0009-2614(86)87157-3 . [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

Colbourn, Dyke, et al., 1978
Colbourn, E.A.; Dyke, J.M.; Fayad, N.K.; Morris, A., The He(I) photoelectron spectra of BrF and IF, J. Electron Spectrosc. Relat. Phenom., 1978, 14, 443. [all data]

Irsa and Friedman, 1958
Irsa, A.P.; Friedman, L., Mass spectra of halogen fluorides, J. Inorg. Nucl. Chem., 1958, 6, 77. [all data]

Dyke, Josland, et al., 1984
Dyke, J.M.; Josland, G.D.; Snijders, J.G.; Boerrigter, P.M., Ionization energies of the diatomic halogens and interhalogens studied with relativistic hartree-fock-slater calculations, Chem. Phys., 1984, 91, 419. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References