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tetrakis(trifluorophosphine)nickel


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-3989.2 ± 9.9kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafliquid-4023.8 ± 9.9kJ/molReviewMartinho Simões 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltavap34.6 ± 0.2kJ/molHAL-HFCBrown and Connor, 1974 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

tetrakis(trifluorophosphine)nickel (l) = nickel (cr) + 4Phosphorus trifluoride (g)

By formula: F12NiP4 (l) = Ni (cr) + 4F3P (g)

Quantity Value Units Method Reference Comment
Deltar194.2 ± 8.4kJ/molHAL-HFCBrown and Connor, 1974 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.82 ± 0.06PEBassett, Higginson, et al., 1974LLK
8.77PEMuller, Fenderl, et al., 1971LLK
8.81EIMuller, Fenderl, et al., 1971LLK
8.7EIKiser, Krassoi, et al., 1967RDSH
9.69PEHillier, Saunders, et al., 1970Vertical value; RDSH
9.6PEGreen, King, et al., 1970Vertical value; RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
NiPF3+14.0?EIKiser, Krassoi, et al., 1967RDSH
NiP2F6+11.4?EIKiser, Krassoi, et al., 1967RDSH
NiP3F9+9.7?EIKiser, Krassoi, et al., 1967RDSH
Ni+17.3?EIKiser, Krassoi, et al., 1967RDSH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Brown and Connor, 1974
Brown, D.L.S.; Connor, J.A., Skinner, H. A. J. Chem. Soc., Faraday Trans. I, 1974, 70, 1649. [all data]

Bassett, Higginson, et al., 1974
Bassett, P.J.; Higginson, B.R.; Lloyd, D.R.; Lynaugh, N.; Roberts, P.J., Helium-I photoelectron spectra of tetrakis(trifluoro- phosphine)-nickel(O), -palladium(O), and -platinum(O), J. Chem. Soc. Dalton Trans., 1974, 2316. [all data]

Muller, Fenderl, et al., 1971
Muller, J.; Fenderl, K.; Mertschenk, B., Die Donor-Akzeptor-Eigenschaften des Liganden Trifluorphosphin in Ubergangsmetallkomplexen, Chem. Ber., 1971, 104, 700. [all data]

Kiser, Krassoi, et al., 1967
Kiser, R.W.; Krassoi, M.A.; Clark, R.J., Mass spectrometric study of tetrakis(trifluorophosphine)nickel(0), J. Am. Chem. Soc., 1967, 89, 3653. [all data]

Hillier, Saunders, et al., 1970
Hillier, I.H.; Saunders, V.R.; Ware, M.J.; Bassett, P.J.; Lloyd, D.R.; Lynaugh, N., On the bonding and the photoelectron spectra of Ni(PF3)4 and Pt(PF3)4, Chem. Commun., 1970, 1316. [all data]

Green, King, et al., 1970
Green, J.C.; King, D.I.; Eland, J.H.D., Photoelectron spectra of trifluorophosphine and its complexes Ni(PF3), and Pt(PF3)4, Chem. Commun., 1970, 1121. [all data]


Notes

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