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Plutonium trifluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to F3Pu+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
8.6 ± 0.5EIKleinschmidt, 1988LL

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
FPu+18.8 ± 0.32FEIKleinschmidt, 1988LL
PuF+17.8 ± 0.5?EIKent, 1968RDSH
F2Pu+12.5 ± 0.2FEIKleinschmidt, 1988LL
PuF2+12.6 ± 0.5FEIKent, 1968RDSH
Pu+25.3 ± 0.23FEIKleinschmidt, 1988LL
Pu+25.0 ± 1.0?EIKent, 1968RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kleinschmidt, 1988
Kleinschmidt, P.D., Thermochemistry of the plutonium fluorides from electron impact studies, J. Chem. Phys., 1988, 89, 6897. [all data]

Kent, 1968
Kent, R.A., Mass spectrometric studies of plutonium compounds at high temperatures. II. The enthalpy of sublimation of plutonium(III) fluoride and the dissociation energy of plutonium(I) fluoride, J. Am. Chem. Soc., 1968, 90, 5657. [all data]


Notes

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