Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Dichloroboron


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

gas 200 260 Lee, Han, et al., 1989

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

gas B,C-X 200 500 Creasey, Hatherly, et al., 1993
Biehl, Creasey, et al., 1995
Boyle, Seccomb, et al., 1999
gas 240 380 Dessaux, Goudmand, et al., 1967
Dessaux, Goudmand, et al.
Suto, Ye, et al., 1988
Lee, Han, et al., 1989
Tokue, Kudo, et al., 1992
gas 280 380 Suto, Ye, et al., 1988
Lee, Han, et al., 1989
Tokue, Kudo, et al., 1992

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

gas A-X 380 650 Suto, Ye, et al., 1988
Lee, Han, et al., 1989
Tokue, Kudo, et al., 1992
Creasey, Hatherly, et al., 1993

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 731 w Ar IR Miller and Andrews, 1980
b2 3 Asym. stretch 977.5 Ne IR Jacox, Irikura, et al., 1996
3 Asym. stretch 976.4 Ne IR Jacox, Irikura, et al., 1996
3 Asym. stretch 965.6 vs Ar IR Miller and Andrews, 1980
Hassanzadeh and Andrews, 1993

Additional references: Jacox, 1994, page 89; Jacox, 1998, page 192; Jacox, 2003, page 133

Notes

wWeak
vsVery strong

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lee, Han, et al., 1989
Lee, L.C.; Han, J.C.; Suto, M., Fluorescence from photoexcitation of BCl3 at 45--106 nm, J. Chem. Phys., 1989, 91, 4, 2036, https://doi.org/10.1063/1.457063 . [all data]

Creasey, Hatherly, et al., 1993
Creasey, J.C.; Hatherly, P.A.; Lambert, I.R.; Tuckett, R.P., Vacuum UV fluorescence excitation spectroscopy of BCl, Mol. Phys., 1993, 79, 2, 413, https://doi.org/10.1080/00268979300101311 . [all data]

Biehl, Creasey, et al., 1995
Biehl, H.; Creasey, J.C.; Smith, D.M.; Tuckett, R.P.; Yoxall, K.R.; Baumgartel, H.; Jochims, H.W.; Rockland, U., J. Chem. Soc., 1995, Faraday Trans. 91, 3073. [all data]

Boyle, Seccomb, et al., 1999
Boyle, K.J.; Seccomb, D.P.; Tuckett, R.P.; Baumgartel, H.; Jochims, H.W., Vacuum-UV fluorescence spectroscopy of BF, J. Phys. B: At. Mol. Opt. Phys., 1999, 32, 11, 2569, https://doi.org/10.1088/0953-4075/32/11/308 . [all data]

Dessaux, Goudmand, et al., 1967
Dessaux, O.; Goudmand, P.; Pannetier, G., Compt. Rend. Acad. Sci. Paris C, 1967, 265, 480. [all data]

Dessaux, Goudmand, et al.
Dessaux, O.; Goudmand, P.; Pannetier, G., Bull. Soc. Chim. Fr. 1969, 447. [all data]

Suto, Ye, et al., 1988
Suto, M.; Ye, C.; Han, J.C.; Lee, L.C., Quantitative absorption and fluorescence spectroscopy of BCl3 in vacuum ultraviolet, J. Chem. Phys., 1988, 89, 11, 6653, https://doi.org/10.1063/1.455387 . [all data]

Tokue, Kudo, et al., 1992
Tokue, I.; Kudo, M.; Kusakabe, M.; Honda, T.; Ito, Y., Emission cross sections of excited fragments produced by electron impact on BCl3, J. Chem. Phys., 1992, 96, 12, 8889, https://doi.org/10.1063/1.462246 . [all data]

Miller and Andrews, 1980
Miller, J.H.; Andrews, L., Matrix photoionization and radiolysis of boron trihalides. Infrared and ultraviolet spectra of boron trichloride(1+) and boron tribromide(1+) and infrared spectra of boron dichloride and boron dibromide, J. Am. Chem. Soc., 1980, 102, 15, 4900, https://doi.org/10.1021/ja00535a011 . [all data]

Jacox, Irikura, et al., 1996
Jacox, M.E.; Irikura, K.K.; Thompson, W.E., Matrix isolation study of the interaction of excited neon atoms with BCl3: Infrared spectra of BCl+3, BCl+2, and BCl-3, J. Chem. Phys., 1996, 104, 22, 8871, https://doi.org/10.1063/1.471622 . [all data]

Hassanzadeh and Andrews, 1993
Hassanzadeh, P.; Andrews, L., Reaction of halogens with laser-ablated boron: infrared spectra of BXn (X = F, Cl, Br, I; n = 1, 2, 3) in solid argon, J. Phys. Chem., 1993, 97, 19, 4910, https://doi.org/10.1021/j100121a008 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References