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P2F4


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
<=9.28PIBerkowitz, Greene, et al., 1984LBLHLM
9.3 ± 0.1EIDean, Finch, et al., 1974LLK
9.64PECradock and Rankin, 1972Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
FP+~17.01F+PF2PIBerkowitz, Greene, et al., 1984LBLHLM
F2P+~10.61PF2PIBerkowitz, Greene, et al., 1984LBLHLM
F2P+10.9 ± 0.1PF2EIDean, Finch, et al., 1974LLK
F3P2+~9.53FPIBerkowitz, Greene, et al., 1984LBLHLM

Mass spectrum (electron ionization)

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin A.Pleshkova, Nesmeyanov Inst.Org.Elem.Cpds, Moscow
NIST MS number 284322

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References

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Berkowitz, Greene, et al., 1984
Berkowitz, J.; Greene, J.P.; Foropoulos, J., Jr.; Neskovic, O.M., Bonding and ionization energies of N-F and P-F compounds, J. Chem. Phys., 1984, 81, 6166. [all data]

Dean, Finch, et al., 1974
Dean, C.R.S.; Finch, A.; Gardner, P.J.; Payling, D.W., Appearance and ionization potentials of ions produced by electron-impact on some phosphorus-fluorine compounds: the phosphorusphorus bond dissociation energy in diphosphorus tetrafluoride, J. Chem. Soc. Faraday Trans. 1, 1974, 70, 1921. [all data]

Cradock and Rankin, 1972
Cradock, S.; Rankin, D.W.H., Photoelectron spectra of PF2H some substituted difluorophosphines, J. Chem. Soc. Faraday Trans. 2, 1972, 68, 940. [all data]


Notes

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References