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P2F4


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
<=9.28PIBerkowitz, Greene, et al., 1984LBLHLM
9.3 ± 0.1EIDean, Finch, et al., 1974LLK
9.64PECradock and Rankin, 1972Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
FP+~17.01F+PF2PIBerkowitz, Greene, et al., 1984LBLHLM
F2P+~10.61PF2PIBerkowitz, Greene, et al., 1984LBLHLM
F2P+10.9 ± 0.1PF2EIDean, Finch, et al., 1974LLK
F3P2+~9.53FPIBerkowitz, Greene, et al., 1984LBLHLM

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Berkowitz, Greene, et al., 1984
Berkowitz, J.; Greene, J.P.; Foropoulos, J., Jr.; Neskovic, O.M., Bonding and ionization energies of N-F and P-F compounds, J. Chem. Phys., 1984, 81, 6166. [all data]

Dean, Finch, et al., 1974
Dean, C.R.S.; Finch, A.; Gardner, P.J.; Payling, D.W., Appearance and ionization potentials of ions produced by electron-impact on some phosphorus-fluorine compounds: the phosphorusphorus bond dissociation energy in diphosphorus tetrafluoride, J. Chem. Soc. Faraday Trans. 1, 1974, 70, 1921. [all data]

Cradock and Rankin, 1972
Cradock, S.; Rankin, D.W.H., Photoelectron spectra of PF2H some substituted difluorophosphines, J. Chem. Soc. Faraday Trans. 2, 1972, 68, 940. [all data]


Notes

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