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Rhenium, pentacarbonyliodo-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Dirhenium decacarbonyl (cr) + Iodine (cr) = 2Rhenium, pentacarbonyliodo- (cr)

By formula: C10O10Re2 (cr) + I2 (cr) = 2C5IO5Re (cr)

Quantity Value Units Method Reference Comment
Deltar-172. ± 18.kJ/molPCHarel and Adamson, 1986The reaction enthalpy was calculated from the enthalpy of the same reaction in cyclohexane, -157. ± 16. kJ/mol, and from the solution enthalpies of Re2(CO)10(cr), 34.3 ± 2.1 kJ/mol, I2(cr), 20.5 ± 0.4 kJ/mol, and Re(CO)5(I)(cr), 34.7 ± 4.2 kJ/mol Harel and Adamson, 1986

Dirhenium decacarbonyl (solution) + Iodine (solution) = 2Rhenium, pentacarbonyliodo- (solution)

By formula: C10O10Re2 (solution) + I2 (solution) = 2C5IO5Re (solution)

Quantity Value Units Method Reference Comment
Deltar-157. ± 16.kJ/molPCHarel and Adamson, 1986solvent: Cyclohexane; Please also see Adamson, Vogler, et al., 1978.

C10MnO10Re (solution) + Iodine (solution) = Rhenium, pentacarbonyliodo- (solution) + Manganese, pentacarbonyliodo- (solution)

By formula: C10MnO10Re (solution) + I2 (solution) = C5IO5Re (solution) + C5IMnO5 (solution)

Quantity Value Units Method Reference Comment
Deltar-233. ± 13.kJ/molPCHarel and Adamson, 1986solvent: Cyclohexane

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.64 ± 0.03EIJunk, Svec, et al., 1968RDSH
8.36PEHigginson, Lloyd, et al., 1975Vertical value; LLK
8.32PEHall, 1975Vertical value; LLK
8.50PECeasar, Milazzo, et al., 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
COIRe+16.694COEIJunk, Svec, et al., 1968RDSH
C2O2IRe+14.653COEIJunk, Svec, et al., 1968RDSH
C3O3IRe+12.042COEIJunk, Svec, et al., 1968RDSH
C3O3Re+14.71?EIJunk, Svec, et al., 1968RDSH
C4O4IRe+10.29COEIJunk, Svec, et al., 1968RDSH
ReI+19.205COEIJunk, Svec, et al., 1968RDSH
Re+>23.?EIJunk, Svec, et al., 1968RDSH

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin B.F.G.JOHNSON DEPT. OF CHEM., UNIV. OF MANCHESTER, UK
NIST MS number 17737

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References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Harel and Adamson, 1986
Harel, Y.; Adamson, A.W., J. Phys. Chem., 1986, 90, 6693. [all data]

Adamson, Vogler, et al., 1978
Adamson, A.W.; Vogler, A.; Kunkely, H.; Wachter, R., J. Am. Chem. Soc., 1978, 100, 1298. [all data]

Junk, Svec, et al., 1968
Junk, G.A.; Svec, H.J.; Angelici, R.J., Electron impact studies of manganese and rhenium pentacarbonyl halides, J. Am. Chem. Soc., 1968, 90, 5758. [all data]

Higginson, Lloyd, et al., 1975
Higginson, B.R.; Lloyd, D.R.; Evans, S.; Orchard, A.F., Photoelectron studies of metal carbonyls. Part 5. - Substituted group VIIA carbonyls, J. Chem. Soc. Faraday Trans. 2, 1975, 71, 1913. [all data]

Hall, 1975
Hall, M.B., The use of spin-orbit coupling in the interpretation of photoelectron spectra. I. Application to substituted rhenium pentacarbonyls, J. Am. Chem. Soc., 1975, 97, 2057. [all data]

Ceasar, Milazzo, et al., 1974
Ceasar, G.P.; Milazzo, P.; Cihonski, J.L.; Levenson, R.A., Photoelectron spectra of osmium and ruthenium tetroxide, J. Am. Chem. Soc., 1974, 13, 3035. [all data]


Notes

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