Aluminum chloride fluoride
- Formula: AlClF2
- Molecular weight: 100.431
- IUPAC Standard InChI: InChI=1S/Al.ClH.2FH/h;3*1H/q+3;;;/p-3
- IUPAC Standard InChIKey: AAYWCFPMITZDSH-UHFFFAOYSA-K
- CAS Registry Number: 13814-65-8
- Chemical structure:
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Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Clustering reactions
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= (
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By formula: Cl- + AlClF2 = (Cl- • AlClF2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 74.3 ± 2.9 | kcal/mol | TDAs | Pervova, Korobov, et al., 1992 | gas phase; Thermo at 0K, experiments at 800-1100K. See also AlCl2F..F-; value altered from reference due to conversion from electron convention to ion convention |
+
= (
•
)
By formula: F- + AlClF2 = (F- • AlClF2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 117.4 ± 2.9 | kcal/mol | TDAs | Pervova, Korobov, et al., 1992 | gas phase; Thermo at 0K, experiments at 800-1100 K; value altered from reference due to conversion from electron convention to ion convention |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Pervova, Korobov, et al., 1992
Pervova, Y.U.; Korobov, M.V.; Sidorov, L.N.,
Enthalpies of Bonds Rupture in AlClnF4-n(-) Anions,
Russ. J. Phys. Chem., 1992, 66, 635. [all data]
Notes
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- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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