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Hexathiane


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to S6+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
3.210 ± 0.070LPDHunsicker, Jones, et al., 1995Vertical Detachment Energy: 3.55 eV. An isomer exists with EA=2.26 eV; B

Ionization energy determinations

IE (eV) Method Reference Comment
9.2 ± 0.2EIRosinger, Grade, et al., 1983LBLHLM
9.00 ± 0.03PIBerkowitz and Lifshitz, 1968RDSH
9.7 ± 0.3EIBerkowitz and Chupka, 1964RDSH
8.5 ± 0.3EIHagemann, 1962RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
S2+12.8 ± 1.0?EIBerkowitz and Chupka, 1964RDSH
S3+13.3 ± 0.5?EIBerkowitz and Chupka, 1964RDSH
S4+11.94 ± 0.05S2PIBerkowitz and Lifshitz, 1968RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunsicker, Jones, et al., 1995
Hunsicker, S.; Jones, R.O.; Gantefor, G., Rings and chains in sulfur cluster anions S- to S-9(-): Theory (simulated annealing) and experiment (photoelectron detachment), J. Chem. Phys., 1995, 102, 15, 5917, https://doi.org/10.1063/1.469326 . [all data]

Rosinger, Grade, et al., 1983
Rosinger, W.; Grade, M.; Hirschwald, W., Detection of ion states of S2 to S8 by electron impact, Int. J. Mass Spectrom. Ion Processes, 1983, 47, 239. [all data]

Berkowitz and Lifshitz, 1968
Berkowitz, J.; Lifshitz, C., Photoionization of high temperature vapors. II. Sulfur molecular species, J. Chem. Phys., 1968, 48, 4346. [all data]

Berkowitz and Chupka, 1964
Berkowitz, J.; Chupka, W.A., Vaporization processes involving sulfur, J. Chem. Phys., 1964, 40, 287. [all data]

Hagemann, 1962
Hagemann, R., Determination de la chaleur de formation de S2O par spectrometrie de masse, Compt. Rend., 1962, 255, 1102. [all data]


Notes

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