europium dichloride


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

(CAS Reg. No. 150238-26-9 • 4294967295Cl2Eu) + Cl2Eu = CAS Reg. No. 150238-26-9

By formula: (CAS Reg. No. 150238-26-9 • 4294967295Cl2Eu) + Cl2Eu = CAS Reg. No. 150238-26-9

Quantity Value Units Method Reference Comment
Δr492. ± 33.kJ/molTDAsKudin, Burdukovskaya, et al., 1993gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
1.53 ± 0.27R-AKudin, Burdukovskaya, et al., 1993B

Ionization energy determinations

IE (eV) Method Reference Comment
8.91 ± 0.05EISapegin, Baluev, et al., 1982LBLHLM
10.5 ± 0.5EIHastie, Ficalora, et al., 1968RDSH
9.92 ± 0.06PELee, Potts, et al., 1982Vertical value; LBLHLM

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
EuCl+10.24 ± 0.05ClEISapegin, Baluev, et al., 1982LBLHLM
EuCl+10.3 ± 0.5ClEIHastie, Ficalora, et al., 1968RDSH
Eu+14.85 ± 0.06?EISapegin, Baluev, et al., 1982LBLHLM
Eu+15.0 ± 0.5?EIHastie, Ficalora, et al., 1968RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kudin, Burdukovskaya, et al., 1993
Kudin, L.S.; Burdukovskaya, G.G.; Butman, M.F.; Krasnov, K.S., Mass-Spectrometric Determination of EuCl2-, EuCl3-, EuCl4- and Eu2Cl7- Gaseous Ion Formation Enthalpies, Zh. Fiz. Khim. SSSR, 1993, 67, 645. [all data]

Sapegin, Baluev, et al., 1982
Sapegin, A.M.; Baluev, A.V.; Evdokimov, V.I., Mass-spectrometric determination of the thermochemical characteristics of europium dichloride, Zh. Fiz. Khim., 1982, 56, 212. [all data]

Hastie, Ficalora, et al., 1968
Hastie, J.W.; Ficalora, P.; Margrave, J.L., Mass spectrometric studies at high temperatures. XXV. Vapor composition over LaCl3, EuCl3 and LuCl3 and stabilities of the trichloride dimers, J. Less-Common Metals, 1968, 14, 83. [all data]

Lee, Potts, et al., 1982
Lee, E.P.F.; Potts, A.W.; Bloor, J.E., HeI and HeII photoelectron spectra of lanthanide trichlorides in the vapour phase, Proc. R. Soc. London A, 1982, 381, 373. [all data]


Notes

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