Germyl radical

• Formula: GeH₃
• Molecular weight: 75.66
• IUPAC Standard InChI: InChI=1S/GeH3/h1H3 Copy

  
• IUPAC Standard InChIKey: WHYHZFHCWGGCOP-UHFFFAOYSA-N Copy
• CAS Registry Number: 13765-45-2
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
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Reaction thermochemistry data

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 (g) =  (g) +  (g)

By formula: H₄Ge (g) = H (g) + H₃Ge (g)

 (g) =  (g) +  (g)

By formula: H₃Ge (g) = H (g) + H₂Ge (g)

 (g) +  (g) =  (g) +  (g)

By formula: I (g) + H₄Ge (g) = HI (g) + H₃Ge (g)

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
B - John E. Bartmess

View reactions leading to H₃Ge⁺ (ion structure unspecified)

Electron affinity determinations

Ionization energy determinations

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   5p ²A₂

State:   X

Additional references: Jacox, 1994, page 128

Notes

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Vibrational and/or electronic energy levels, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Berkowitz, Ellison, et al., 1994
Berkowitz, J.; Ellison, G.B.; Gutman, D., Three methods to measure RH bond energies, J. Phys. Chem., 1994, 98, 2744. [all data]

Ruscic, Schwarz, et al., 1990
Ruscic, B.; Schwarz, M.; Berkowitz, J., Photoionization studies of GeH_n(n = 2-4), J. Chem. Phys., 1990, 92, 1865. [all data]

Noble and Walsh, 1983
Noble, P.N.; Walsh, R., Kinetics of the gas phase reaction between iodine and monogermane and the bond dissociation energy D(H₃Ge-H), Int. J. Chem. Kinet., 1983, 15, 547. [all data]

Decouzon, Gal, et al., 1993
Decouzon, M.; Gal, J.F.; Gayraud, J.; Maria, P.C.; Vaglio, G.A.; Volpe, P., Fourier Transform-Ion Cyclotron Resonance Study of the Gas-Phase Acidities of Germane and Methylgermane - Bond Dissociation Energy of German, J. Am. Soc. Mass Spectrom., 1993, 4, 1, 54, https://doi.org/10.1016/1044-0305(93)85042-V . [all data]

Mayer, Gal, et al., 1997
Mayer, P.M.; Gal, J.-F.; Radom, L., The Heats of Formation, Gas-phase Acidities, and Related Thermochemical Properties of the Third-row Hydrides GeH4, AsH3, SeH2, and HBr from G2 ab initio Calculations, Int. J. Mass Spectrom. Ion Proc., 1997, 167/168, 689, https://doi.org/10.1016/S0168-1176(97)00127-4 . [all data]

Reed and Brauman, 1974
Reed, K.J.; Brauman, J.I., Photodetachment of electrons from Group IVa binary hydride anions: The electron affinities of the SiH₃ and GeH₃ radicals, J. Chem. Phys., 1974, 61, 4830. [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

Johnson, Tsai, et al., 1988
Johnson, R.D., III; Tsai, B.P.; Hudgens, J.W., The electronic spectrum of the GeH3 radical, J. Chem. Phys., 1988, 89, 8, 4558, https://doi.org/10.1063/1.454796 . [all data]

Wang, Andrews, et al., 2002
Wang, X.; Andrews, L.; Kushto, G.P., Infrared Spectra of the Novel Ge, J. Phys. Chem. A, 2002, 106, 24, 5809, https://doi.org/10.1021/jp020219v . [all data]

Quandt and Hershberger, 1995
Quandt, R.W.; Hershberger, J.F., Kinetics of GeH3 reactions with NO, NO2, and O2, Chem. Phys. Lett., 1995, 233, 5-6, 559, https://doi.org/10.1016/0009-2614(94)01510-3 . [all data]

Wang and Andrews, 2003
Wang, X.; Andrews, L., Infrared Spectra of Group 14 Hydrides in Solid Hydrogen: Experimental Observation of PbH, J. Am. Chem. Soc., 2003, 125, 21, 6581, https://doi.org/10.1021/ja029862l . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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• Symbols used in this document:
  

  EA	Electron affinity
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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