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Van Den Dool and Kratz RI, non-polar column, temperature ramp

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryPackedPackedPacked
Active phase SPB-1CBP-1Methyl SiliconeMethyl SiliconeMethyl Silicone
Column length (m) 30.12.   
Carrier gas HeN2   
Substrate      
Column diameter (mm) 0.750.53   
Phase thickness (mum) 1.0    
Tstart (C) 160.120.120.120.120.
Tend (C) 280.250.290.290.290.
Heat rate (K/min) 10.6.7.7.7.
Initial hold (min)   4.4.4.
Final hold (min) 12. 10.10.10.
I 1884.1838.1881.1890.1880.
ReferenceChrist, Noomano, et al., 1988Oyama, Sano, et al., 1987Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedPacked
Active phase Methyl SiliconeMethyl SiliconeMethyl SiliconeMethyl SiliconeMethyl Silicone
Column length (m)      
Carrier gas      
Substrate      
Column diameter (mm)      
Phase thickness (mum)      
Tstart (C) 120.120.120.120.120.
Tend (C) 290.290.290.290.290.
Heat rate (K/min) 7.7.7.7.7.
Initial hold (min) 4.4.4.4.4.
Final hold (min) 10.10.10.10.10.
I 1880.1882.1882.1882.1882.
ReferenceBogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedPacked
Active phase Methyl SiliconeMethyl SiliconeMethyl SiliconeMethyl SiliconeMethyl Silicone
Column length (m)      
Carrier gas      
Substrate      
Column diameter (mm)      
Phase thickness (mum)      
Tstart (C) 120.120.120.120.120.
Tend (C) 290.290.290.290.290.
Heat rate (K/min) 7.7.7.7.7.
Initial hold (min) 4.4.4.4.4.
Final hold (min) 10.10.10.10.10.
I 1885.1885.1890.1892.1895.
ReferenceBogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedPacked
Active phase Methyl SiliconeMethyl SiliconeMethyl SiliconeMethyl SiliconeMethyl Silicone
Column length (m)      
Carrier gas      
Substrate      
Column diameter (mm)      
Phase thickness (mum)      
Tstart (C) 120.120.120.120.120.
Tend (C) 290.290.290.290.290.
Heat rate (K/min) 7.7.7.7.7.
Initial hold (min) 4.4.4.4.4.
Final hold (min) 10.10.10.10.10.
I 1865.1882.1885.1885.1885.
ReferenceBogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedPacked
Active phase Methyl SiliconeMethyl SiliconeMethyl SiliconeMethyl SiliconeMethyl Silicone
Column length (m)      
Carrier gas      
Substrate      
Column diameter (mm)      
Phase thickness (mum)      
Tstart (C) 120.120.120.120.120.
Tend (C) 290.290.290.290.290.
Heat rate (K/min) 7.7.7.7.7.
Initial hold (min) 4.4.4.4.4.
Final hold (min) 10.10.10.10.10.
I 1885.1885.1890.1890.1890.
ReferenceBogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedPacked
Active phase Methyl SiliconeMethyl SiliconeMethyl SiliconeMethyl SiliconeMethyl Silicone
Column length (m)      
Carrier gas      
Substrate      
Column diameter (mm)      
Phase thickness (mum)      
Tstart (C) 120.120.120.120.120.
Tend (C) 290.290.290.290.290.
Heat rate (K/min) 7.7.7.7.7.
Initial hold (min) 4.4.4.4.4.
Final hold (min) 10.10.10.10.10.
I 1893.1895.1875.1875.1875.
ReferenceBogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedPacked
Active phase Methyl SiliconeMethyl SiliconeMethyl SiliconeMethyl SiliconeMethyl Silicone
Column length (m)      
Carrier gas      
Substrate      
Column diameter (mm)      
Phase thickness (mum)      
Tstart (C) 120.120.120.120.120.
Tend (C) 290.290.290.290.290.
Heat rate (K/min) 7.7.7.7.7.
Initial hold (min) 4.4.4.4.4.
Final hold (min) 10.10.10.10.10.
I 1875.1875.1880.1880.1880.
ReferenceBogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedCapillary
Active phase Methyl SiliconeMethyl SiliconeMethyl SiliconeMethyl SiliconeDB-1
Column length (m)     15.
Carrier gas     He
Substrate      
Column diameter (mm)     0.32
Phase thickness (mum)     0.25
Tstart (C) 120.120.120.120.120.
Tend (C) 290.290.290.290.280.
Heat rate (K/min) 7.7.7.7.8.
Initial hold (min) 4.4.4.4. 
Final hold (min) 10.10.10.10.5.
I 1880.1880.1885.1895.1854.
ReferenceBogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Bogusz, Wijsbeek, et al., 1985Perrigo, Peel, et al., 1985
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Methyl SiliconeDB-1DB-1DB-1DB-1
Column length (m) 12.15.15.15.15.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.20.250.250.250.25
Phase thickness (mum) 0.330.250.250.250.25
Tstart (C) 50.120.120.120.120.
Tend (C) 300.280.280.280.280.
Heat rate (K/min) 20.8.12.15.5.
Initial hold (min) 1.    
Final hold (min) 3.5.5.5.5.
I 1852.01854.1860.1863.1848.
ReferenceNewton and Foery, 1984Perrigo, Ballantyne, et al., 1984Perrigo, Ballantyne, et al., 1984Perrigo, Ballantyne, et al., 1984Perrigo, Ballantyne, et al., 1984
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPacked
Active phase SE-30SE-30
Column length (m) 15.1.8
Carrier gas HeN2
Substrate  Chromosorb W
Column diameter (mm) 0.25 
Phase thickness (mum) 0.25 
Tstart (C) 100.130.
Tend (C) 295.290.
Heat rate (K/min) 5.8.
Initial hold (min)  2.
Final hold (min)  8.
I 1842.1865.
ReferenceAnderson and Stafford, 1983Perrigo and Peel, 1981
Comment MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Christ, Noomano, et al., 1988
Christ, D.W.; Noomano, P.; Rosas, M.; Rhone, D., Retention indices by wide-bore capillary gas chromatography with nitrogen-phosphorus detection, J. Anal. Toxicol., 1988, 12, 2, 84-88, https://doi.org/10.1093/jat/12.2.84 . [all data]

Oyama, Sano, et al., 1987
Oyama, N.; Sano, T.; Syoyama, M.; Maeda, K., Studies on systematic analysis of poisonous compounds in forensic chemistry. II. Application of capillary column gas chromatography to substance identification by means of retention indices, Eisei Kagaku, 1987, 33, 5, 342-348, https://doi.org/10.1248/jhs1956.33.342 . [all data]

Bogusz, Wijsbeek, et al., 1985
Bogusz, M.; Wijsbeek, J.; Franke, J.P.; de Zeeuw, R.A.; Gierz, J., Impact of biological matrix, drug concentration, and method of isolation on detectability and variability of retention index values in gas chromatography, J. Anal. Toxicol., 1985, 9, 2, 49-54, https://doi.org/10.1093/jat/9.2.49 . [all data]

Perrigo, Peel, et al., 1985
Perrigo, B.J.; Peel, H.W.; Ballantyne, D.J., Use of Dual-Column Fused-Silica Capillary Gas Chromatography in Combination with Detector Response Factors for Analytical Toxicology., J. Chromatogr., 1985, 341, 81-88, https://doi.org/10.1016/S0378-4347(00)84011-6 . [all data]

Newton and Foery, 1984
Newton, B.; Foery, R.F., Retention indices and dual capillary gas chromatography for rapid identification of sedative hypnotic drugs in emergency toxicology, J. Anal. Toxicol., 1984, 8, 3, 129-134, https://doi.org/10.1093/jat/8.3.129 . [all data]

Perrigo, Ballantyne, et al., 1984
Perrigo, B.J.; Ballantyne, D.J.; Peel, H.W., Condierations in developing a data base for drugs on a DBI capillary column, J. Can. Soc. Forensic Sci., 1984, 17, 2, 41-49, https://doi.org/10.1080/00085030.1984.10757360 . [all data]

Anderson and Stafford, 1983
Anderson, W.H.; Stafford, D.T., Applications of capillary gas chromatography in routine toxicological analyses, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1983, 6, 5, 247-254, https://doi.org/10.1002/jhrc.1240060506 . [all data]

Perrigo and Peel, 1981
Perrigo, B.J.; Peel, H.W., The use of retention indices and temperature-programmed gas chromatography in analytical toxicology, J. Chromatogr. Sci., 1981, 19, 5, 219-226, https://doi.org/10.1093/chromsci/19.5.219 . [all data]


Notes

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References