Benzene, 1,2-diethyl-4-methyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tboil475.KN/AKunckell and Ulex. G., 1913Uncertainty assigned by TRC = 4. K

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryOV-1100.1154.2Matisová and Kurán, 199052. m/0.25 mm/0.38 μm, N2
CapillaryOV-1100.1153.9Matisová and Kurán, 199052. m/0.25 mm/0.38 μm, H2
CapillaryPONA100.1154.9Matisová and Kurán, 199050. m/0.2 mm/0.5 μm, H2
CapillaryOV-101100.1154.Matisová, Kovacicová, et al., 1989He; Column length: 50. m; Column diameter: 0.20 mm
CapillaryOV-101120.1150.Matisová, Moravcová, et al., 1988N2; Column length: 278. m; Column diameter: 0.25 mm
CapillaryApolane120.1159.Matisová, Moravcová, et al., 1988N2; Column length: 200. m; Column diameter: 0.25 mm
CapillaryOV-101100.1144.Matisová, Rukríglová, et al., 1988H2; Column length: 278. m; Column diameter: 0.25 mm

Kovats' RI, polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryCarbowax 20M90.1384.6Döring, Estel, et al., 1974Column length: 100. m; Column diameter: 0.2 mm

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryOV-11153.Orav, Kailas, et al., 19992. K/min; Tstart: 50. C; Tend: 160. C

Normal alkane RI, polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryPEG-40M100.1420.Nesterov, Nesterova, et al., 2000Column length: 50. m
CapillaryPEG-40M100.1422.Nesterov, Nesterova, et al., 2000Column length: 50. m
CapillaryPEG-40M120.1435.Nesterov, Nesterova, et al., 2000Column length: 50. m
CapillaryPEG-40M140.1453.Nesterov, Nesterova, et al., 2000Column length: 50. m
CapillaryPEG-40M160.1464.Nesterov, Nesterova, et al., 2000Column length: 50. m
CapillaryPEG-40M80.1409.Nesterov, Nesterova, et al., 2000Column length: 50. m
CapillaryCarbowax 20M90.1385.Sutter, Peterson, et al., 1997 

Normal alkane RI, polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryCarbowax 20M1385.Ivanciuc, Ivanciuc, et al., 2001Program: not specified

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kunckell and Ulex. G., 1913
Kunckell, F.; Ulex. G., Rational Preparation of SOme Benzene Homologs, J. Prakt. Chem., 1913, 87, 227. [all data]

Matisová and Kurán, 1990
Matisová, E.; Kurán, P., Reproducibility of retention indices measurement of alkylbenzenes on crosslinked methyl silicone phase fused silica capillaries, Chromatographia, 1990, 30, 5/6, 328-332, https://doi.org/10.1007/BF02319717 . [all data]

Matisová, Kovacicová, et al., 1989
Matisová, E.; Kovacicová, E.; Ha, P.T.; Kolek, E.; Engewald, W., Identification of alkylbenzenes up to C12 by capillary gas chromatography-mass spectrometry. II. Retention indices on OV-101 columns and retention-molecular structure correlations, J. Chromatogr., 1989, 475, 2, 113-123, https://doi.org/10.1016/S0021-9673(01)89667-9 . [all data]

Matisová, Moravcová, et al., 1988
Matisová, E.; Moravcová, A.; Krupcík; Cellár, P.; Leclercq, P.A., Problems with the reproducibility of retention data on capillary columns with hydrocarbon C87 as the stationary phase, J. Chromatogr., 1988, 454, 65-71, https://doi.org/10.1016/S0021-9673(00)88602-1 . [all data]

Matisová, Rukríglová, et al., 1988
Matisová, E.; Rukríglová, M.; Krupcík, J.; Kovacicová, E.; Holotík, S., Identification of alkylbenzenes up to C12 by capillary gas chromatography and combined gas chromatography-mass spectrometry. I. OV-101 as stationary phase, J. Chromatogr., 1988, 455, 301-309, https://doi.org/10.1016/S0021-9673(01)82129-4 . [all data]

Döring, Estel, et al., 1974
Döring, C.E.; Estel, D.; Fischer, R., Kapillar-gaschromatographische Charakterisierung von C10-bis C12-Aromaten, J. Prakt. Chem., 1974, 316, 1, 1-12, https://doi.org/10.1002/prac.19743160102 . [all data]

Orav, Kailas, et al., 1999
Orav, A.; Kailas, T.; Muurisepp, M.; Kann, J., Composition of the oil from waste tires. 2. Fraction boiling at 160-180 0C, Proc. Estonian Acad. Sci. Chem., 1999, 48, 3, 136-140. [all data]

Nesterov, Nesterova, et al., 2000
Nesterov, I.A.; Nesterova, T.N.; Pimerzin, A.A.; Tsvetkov, V.S., Thermodynamics of alkylbenzene sorption and evaporation. IV. Enthalpies of evaporation and thermodynamics chracteristics of sorption by stationary phases OV-101 and PEG-40M, Izvestia vysshikh uchebnykh zavedenii. Khimia i khimicheskaia tekhnologia (Chemistry and chemical technology), 2000, 43, 4, 39-45. [all data]

Sutter, Peterson, et al., 1997
Sutter, J.M.; Peterson, T.A.; Jurs, P.C., Prediction of gas chromatographic retention indices of alkylbenzenes, Anal. Chim. Acta., 1997, 342, 2-3, 113-122, https://doi.org/10.1016/S0003-2670(96)00578-8 . [all data]

Ivanciuc, Ivanciuc, et al., 2001
Ivanciuc, O.; Ivanciuc, T.; Klein, D.J.; Seitz, W.A.; Balaban, A.T., Quantitative structure-retention relationships for gas chromatographic retention indices of alkylbenzenes with molecular graph descriptors, SAR QSAR Environ. Res., 2001, 11, 5-6, 419-452, https://doi.org/10.1080/10629360108035362 . [all data]


Notes

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