Dimethyldithiocarbamic acid,copper salt


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub37.28 ± 0.07kcal/molCRibeiro da Silva, Reis, et al., 1995 

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Reference Comment
35.23458.Dykyj, Svoboda, et al., 1999Based on data from 443. to 473. K.

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
35.2 ± 0.2458.AStephenson and Malanowski, 1987Based on data from 443. to 473. K. See also Tavlaridis and Neeb, 1978.

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-IW- 981
NIST MS number 230258

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ribeiro da Silva, Reis, et al., 1995
Ribeiro da Silva, M.A.V.; Reis, A.M.M.V.; Faria, R.I.M.C.P., Standard enthalpies of formation of crystalline dimethylammoniumdimethyldithiocarbamate and dimethyldithiocarbamate complexes of copper(II) and nickel(II). The mean Cu-S and Ni-S bond-dissociation enthalpies, J. Chem. Thermodyn., 1995, 27, 1365-1372. [all data]

Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R., Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Tavlaridis and Neeb, 1978
Tavlaridis, Athanassios; Neeb, Rolf, Dialkyldithiocarbamates as reagents for the gas-chromatographic determination of metals, Z. Anal. Chem., 1978, 293, 3, 211-219, https://doi.org/10.1007/BF00491050 . [all data]


Notes

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