Tetramethylthiuram disulfide

• Formula: C₆H₁₂N₂S₄
• Molecular weight: 240.433
• IUPAC Standard InChI: InChI=1S/C6H12N2S4/c1-7(2)5(9)11-12-6(10)8(3)4/h1-4H3 Copy

  
• IUPAC Standard InChIKey: KUAZQDVKQLNFPE-UHFFFAOYSA-N Copy
• CAS Registry Number: 137-26-8
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Bis(dimethylthiocarbamoyl) disulfide; Thioperoxydicarbonic diamide ([(H2N)C(S)]2S2), tetramethyl-; Disulfide, bis(dimethylthiocarbamoyl); Aapirol; Aatiram; Accel TMT; Accelerator T; Accelerator Thiuram; Aceto TETD; Arasan; Arasan 42S; Arasan 70; Arasan 70-S Red; Arasan 75; Arasan-M; Arasan-SF; Atiram; Bis(dimethylthiocarbamyl) disulfide; Cyuram DS; Ekagom TB; Falitiram; Fernasan; Fernasan A; Fernide; Formalsol; Hermal; Hermat TMT; Heryl; Hexathir; Kregasan; Mercuram; Methyl Tuads; Methyl Thiram; Nobecutan; Normersan; Panoram 75; Polyram ultra; Pomarsol; Pomarsol Forte; Pomasol; Puralin; Rezifilm; Royal TMTD; Sadoplon; Sadoplon 75; Spotrete; SQ 1489; Tersan; Tetramethylthiuram Bisulfide; Tetrasipton; Thillate; Thiosan; Thioscabin; Thiotox; Thiram B; Thiram 75; Thiram 80; Thirasan; Thiulin; Thiurad; Thiuram; Thiuram disulfide, tetramethyl-; Thiuram D; Thiuram M; Thiuramyl; Thylate; Tiuramyl; Trametan; Tridipam; Tripomol; Tuads; TUEX; Tulisan; Tutan; TMTD; TMTDS; Vulcafor TMT; Vulcafor TMTD; Vulkacit thiuram; Vulkacit TH; VUagT-I-4; Zaprawa Nasienna T; Tetramethylthiuram disulphide; α,α'-Dithiobis(dimethylthio)formamide; Arasan-sf-x; Bis(dimethyl-thiocarbamoyl)-disulfid; Bis((dimethylamino)carbonothioyl) disulfide; Disolfuro di tetrametiltiourame; Disulfure de tetramethylthiourame; Fermide; Fernacol; Formamide, 1,1'-dithiobis(N,N-dimethylthio-; Methylthiuram disulfide; N,N-Tetramethylthiuram disulfide; N,N,N',N'-Tetramethylthiuram disulfide; N,N'-(Dithiodicarbonothioyl)bis(N-methylmethanamine); Nomersan; Teramethylthiuram disulfide; Tersan 75; Tersantetramethyldiurane sulfide; Tetramethyl-thiram disulfid; Tetramethylenethiuram disulfide; Tetramethylthiocarbamoyldisulphide; Tetramethylthioperoxydicarbonic diamide; Tetramethylthioramdisulfide; Tetramethylthiuram; Tetramethylthiurane disulfide; Tetramethylthiurum disulfide; Tetrathiuram disulfide; Thiotex; Thiramad; Thirame; Thiulix; Thiuram M rubber accelerator; Tirampa; Tiuram; Tyradin; Vancida TM-95; Vulkacit MTIC; Accelerant T; Anles; Arasan 50 red; Basultra; Agrichem flowable thiram; Akrochem TMTD; Aules; Chipco thiram 75; ENT-987; Fermide 850; Naftocit thiuram 16; NSC-1771; Perkacit TMTD; Spotrete-F; Spotrete WP 75; Tetrapom; Thimer; Thioknock; Thiuramin; Vancide TM; Vancide TM-95; Vulkazam S; Vulkacit DTMT; Thioperoxydicarbonic diamide ([(H2N)C(S)]2S2), N,N,N',N'-tetramethyl-; Bis(dimethylaminothiocarbonyl)disulfide; Betoxin; Nocceler TT; Radothiram; Tiradin; Thiram; Robac TMT
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Condensed phase thermochemistry data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • UV/Visible spectrum
  • Gas Chromatography
  • References
  • Notes
• Options:
  • Switch to calorie-based units

Data at NIST subscription sites:

• NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.

Condensed phase thermochemistry data

Go To: Top, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of solid

IR Spectrum

Go To: Top, Condensed phase thermochemistry data, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, References, Notes

Data compiled by: Coblentz Society, Inc.

• SOLID (OIL MULL) $$SPECTRAL CONTAMINATION DUE TO OIL AROUND 2900, 1490 CM^-1; BAIRD (PRISM); DIGITIZED BY COBLENTZ SOCIETY (BATCH II) FROM HARD COPY; 2 cm^-1 resolution

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

• gas; HP-GC/MS/IRD

Mass spectrum (electron ionization)

Go To: Top, Condensed phase thermochemistry data, IR Spectrum, UV/Visible spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

For Zoom

1.) Enter the desired X axis range (e.g., 100, 200)

2.) Check here for automatic Y scaling

3.) Press here to zoom

Additional Data

UV/Visible spectrum

Go To: Top, Condensed phase thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Alexander N. Yermakov, Alexy A. Usov, Antonina A. Goncharova, Axlexander N. Leskin, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

For Zoom

1.) Enter the desired X axis range (e.g., 100, 200)

2.) Check here for automatic Y scaling

3.) Press here to zoom

Additional Data

Gas Chromatography

Go To: Top, Condensed phase thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

View large format table.

References

Go To: Top, Condensed phase thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Good, Lacina, et al., 1961
Good, W.D.; Lacina, J.L.; McCullough, J.P., Tetramethylthiuram monosulfide and tetramethylthiuram disulfide: Heats of formation by rotating-bomb calorimetry; the s-s thermochemical bond energy, J. Phys. Chem., 1961, 65, 860-862. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Fihtengolts, et al., 1969
Fihtengolts, V.S., et al., Atlas of UV Absorption Spectra of Substances Used in Synthetic Rubber Manufacture, 1969, 148. [all data]

Erdmann, Rochholz, et al., 1992
Erdmann, F.; Rochholz, G.; Schütz, H., Retention-indices on OV-1 of approximately 170 commonly used pesticides, Mikrochim. Acta, 1992, 106, 3-6, 219-226, https://doi.org/10.1007/BF01242093 . [all data]

Notes

Go To: Top, Condensed phase thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, References

• Symbols used in this document:
  

  Cp,solid	Constant pressure heat capacity of solid
  ΔcH°solid	Enthalpy of combustion of solid at standard conditions
  ΔfH°solid	Enthalpy of formation of solid at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.