xenon tetrafluoride

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to F4Xe+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)12.7 ± 0.1eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
<=12.72PEBrundle, Jones, et al., 1971LLK
12.7 ± 0.1PIBerkowitz, Chupka, et al., 1971LLK
12.9 ± 0.1EISvec and Flesch, 1963RDSH
13.1SNielsen and Schwarz, 1976Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
XeF+15.813FPIBerkowitz, Chupka, et al., 1971LLK
XeF2+<=15.222FPIBerkowitz, Chupka, et al., 1971LLK
XeF3+13.10FPIBerkowitz, Chupka, et al., 1971LLK
XeF3+13.1 ± 0.1FEISvec and Flesch, 1963RDSH
Xe+12.4 ± 0.1F2+F+F-?EISvec and Flesch, 1963RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brundle, Jones, et al., 1971
Brundle, C.R.; Jones, G.R.; Basch, H., He I and He II photoelectron spectra and the electronic structures of XeF2, XeF4, and XeF6, J. Chem. Phys., 1971, 55, 1098. [all data]

Berkowitz, Chupka, et al., 1971
Berkowitz, J.; Chupka, W.A.; Guyon, P.M.; Holloway, J.H.; Spohr, R., Photoionization mass spectrometric study of XeF2, XeF4, and XeF6, J. Phys. Chem., 1971, 75, 1461. [all data]

Svec and Flesch, 1963
Svec, H.J.; Flesch, G.D., Thermochemical properties of xenon difluoride and xenon tetrafluoride from massspectra, Science, 1963, 142, 954. [all data]

Nielsen and Schwarz, 1976
Nielsen, U.; Schwarz, W.H.E., VUV spectra of the xenon fluorides, Chem. Phys., 1976, 13, 195. [all data]


Notes

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