thorium tetrafluoride

• Formula: F₄Th
• Molecular weight: 308.03167
• CAS Registry Number: 13709-59-6
• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Ion clustering data
  • References
  • Notes
• Data at other public NIST sites:
  • X-ray Photoelectron Spectroscopy Database, version 5.0
• Options:
  • Switch to SI units

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 + F₄Th = ( • F₄Th)

By formula: F^- + F₄Th = (F^- • F₄Th)

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
LL - Sharon G. Lias and Joel F. Liebman

Ionization energy determinations

Appearance energy determinations

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

 + F₄Th = ( • F₄Th)

By formula: F^- + F₄Th = (F^- • F₄Th)

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sidirov, Zhuravlena, et al., 1983
Sidirov, L.N.; Zhuravlena, L.V.; Varkov, M.V.; Skokan, E.V.; Sorokin, I.D.; Koronev, Yu.M.; Akishima, P.A., Mass- spectrometric determination of enthalpies of dissociation of gaseous complex fluorides into neutral and charged particles. VII. MF-ThF₄ systems, Int. J. Mass Spectrom. Ion Processes, 1983, 51, 291. [all data]

Zmbov, 1970
Zmbov, K.F., Heats of formation of gaseous ThF₃ and ThF₂ from mass spectrometric studies, J. Inorg. Nucl. Chem., 1970, 32, 1381. [all data]

Dyke, Josland, et al., 1981
Dyke, J.M.; Josland, G.D.; Morris, A.; Tucker, P.M.; Tyler, J.W., Study of the valence-electronic structure of UF₄, ThF₄, UCl₄ and ThCl₄ in the gas phase and in the solid state, J. Chem. Soc. Faraday Trans. 2, 1981, 77, 1273. [all data]

Lau, Brittain, et al., 1989
Lau, K.H.; Brittain, R.D.; Hildenbrand, D.L., High temperature thermodynamic studies of some gaseous thorium fluorides, J. Chem. Phys., 1989, 90, 1158. [all data]

Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References

• Symbols used in this document:
  

  AE	Appearance energy
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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