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Cobalt, nonacarbonyl[«mu»3-(chloromethylidyne)]tri-, triangulo


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-253.0 ± 1.8kcal/molReviewMartinho SimõesThe enthalpy of formation relies on -4.45 ± 0.1 kcal/mol for the enthalpy of formation of Cl2 in a carbon tetrachloride solution Gardner, Cartner, et al., 1975

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafsolid-281.1 ± 1.7kcal/molReviewMartinho SimõesThe enthalpy of formation relies on -4.45 ± 0.1 kcal/mol for the enthalpy of formation of Cl2 in a carbon tetrachloride solution Gardner, Cartner, et al., 1975

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltasub28.11 ± 0.60kcal/molN/APilcher and Skinner, 1983See also Cardner, Gartner, et al., 1975.; AC
Deltasub28.11 ± 0.60kcal/molRSCGardner, Cartner, et al., 1975MS

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
7.9PEGranozzi, Tondello, et al., 1982LBLHLM
7.8PECosta, Lloyd, et al., 1982LBLHLM
7.7PEChesky and Hall, 1981LLK
8.63PEGranozzi, Tondello, et al., 1982Vertical value; LBLHLM
8.11 ± 0.05PECosta, Lloyd, et al., 1982Vertical value; LBLHLM
8.8PEChesky and Hall, 1981Vertical value; LLK

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 156638

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Gardner, Cartner, et al., 1975
Gardner, P.J.; Cartner, A.; Cunninghame, R.G.; Robinson, B.H., J. Chem. Soc., Dalton Trans., 1975, 2582.. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Cardner, Gartner, et al., 1975
Cardner, Peter J.; Gartner, Anthony; Cunninghame, Robert G.; Robinson, Brian H., Bond energies in dicobalt octacarbonyl and bromo- and chloro-methylidynetricobalt enneacarbonyls, J. Chem. Soc., Dalton Trans., 1975, 23, 2582, https://doi.org/10.1039/dt9750002582 . [all data]

Granozzi, Tondello, et al., 1982
Granozzi, G.; Tondello, E.; Ajo, D.; Casarin, M.; Aime, S.; Osella, D., Gas phase helium I photoelectron spectra of methinyltricobalt enneacarbonyl clusters, Inorg. Chem., 1982, 21, 1081. [all data]

Costa, Lloyd, et al., 1982
Costa, N.C.V.; Lloyd, D.R.; Brint, P.; Pelin, W.K.; Spalding, T.R., The photoelectron spectra of enneacarbonyl-«eta»3-methylidyne- tricobalt and some derivatives, J. Chem. Soc. Dalton Trans., 1982, 201. [all data]

Chesky and Hall, 1981
Chesky, P.T.; Hall, M.B., Electronic structure of metal clusters. 1. Photoelectron spectra and molecular orbital calculations on (alkylidyne)tricobalt nonacarbonyl clusters, Inorg. Chem., 1981, 20, 4419. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References