Chloryl fluoride
- Formula: ClFO2
- Molecular weight: 86.450
- CAS Registry Number: 13637-83-7
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| >2.29999 | EIAE | Alekseev, Fedorova, et al., 1983 | From ClO3F; G3MP2B3 calculations indicate an EA of ca. 1.1 eV; B |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 12.41 ± 0.10 | EI | Baluev, Nikitina, et al., 1980 | LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| ClO+ | 13.41 ± 0.08 | ? | EI | Baluev, Nikitina, et al., 1980 | LLK |
| ClO2+ | 13.15 ± 0.08 | F | EI | Baluev, Nikitina, et al., 1980 | LLK |
| O2+ | 12.16 ± 0.05 | ? | EI | Baluev, Nikitina, et al., 1980 | LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Alekseev, Fedorova, et al., 1983
Alekseev, V.I.; Fedorova, L.I.; Baluev, A.V.,
Mass Spectrometric Study of Thermochemical Characteristics of Perchloryl Fluoride and its Decomposition Product Chlorosyl Fluoride, Izv. Akad. Nauk SSR Ser. Khim. 1084, 1983. [all data]
Baluev, Nikitina, et al., 1980
Baluev, A.V.; Nikitina, Z.K.; Fedorova, L.I.; Rosolovskii, V.Ya.,
Mass spectrometric investigation of electron-impact induced ionization of chlorine dioxide and chloryl fluoride molecules,
Izv. Akad. Nauk SSSR, Ser. Khim., 1980, 1963. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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