SSO+

Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 64400 ± 1000 gas Bock, Solouki, et al., 1973
Rosmus, Dacre, et al., 1974

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 42600 ± 320 gas Frost, Lee, et al., 1973
Bock, Solouki, et al., 1973
Rosmus, Dacre, et al., 1974

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 34700 ± 320 gas Frost, Lee, et al., 1973
Bock, Solouki, et al., 1973
Rosmus, Dacre, et al., 1974

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 33080 ± 320 gas Frost, Lee, et al., 1973
Bock, Solouki, et al., 1973
Rosmus, Dacre, et al., 1974

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 6132 ± 40 gas Frost, Lee, et al., 1973
Bock, Solouki, et al., 1973
Rosmus, Dacre, et al., 1974
Norwood and Ng, 1989
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 SO stretch 915 ± 20 gas PE PI Frost, Lee, et al., 1973
Norwood and Ng, 1989

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 5665 ± 40 gas Frost, Lee, et al., 1973
Bock, Solouki, et al., 1973
Rosmus, Dacre, et al., 1974
Norwood and Ng, 1989
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 SO stretch 923 ± 20 gas PE PI Frost, Lee, et al., 1973
Norwood and Ng, 1989

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 3 SS stretch 480 ± 20 gas PE PI Frost, Lee, et al., 1973
Berkowitz, Eland, et al., 1977
Norwood and Ng, 1989

Additional references: Jacox, 1994, page 97

Notes

xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bock, Solouki, et al., 1973
Bock, H.; Solouki, B.; Rosmus, P.; Steudel, R., Photoelektronen-Spektren und Moleküleigenschaften: SSO versus OSO, Angew. Chem., 1973, 85, 22, 987, https://doi.org/10.1002/ange.19730852212 . [all data]

Rosmus, Dacre, et al., 1974
Rosmus, P.; Dacre, P.D.; Solouki, B.; Bock, H., Hartree-Fock calculations photoelectron spectra of SSO NSF, Theor. Chim. Acta, 1974, 35, 129. [all data]

Frost, Lee, et al., 1973
Frost, D.C.; Lee, S.T.; McDowell, C.A., The HeI photoelectron spectrum of S2O, Chem. Phys. Lett., 1973, 22, 243. [all data]

Norwood and Ng, 1989
Norwood, K.; Ng, C.Y., Photoion-photoelectron coincidence spectroscopy of the transient molecules SO and S2O, Chem. Phys. Lett., 1989, 156, 145. [all data]

Berkowitz, Eland, et al., 1977
Berkowitz, J.; Eland, J.H.D.; Appelman, E.H., Photoionization mass spectrometry and heat of formation of S2O, J. Chem. Phys., 1977, 66, 2183. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

Go To: Top, Vibrational and/or electronic energy levels, References