3-Carene

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas19. ± 4.kJ/molCcbKozina, Aleshina, et al., 1975 

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-29.5 ± 1.9kJ/molCcbKozina, Aleshina, et al., 1975 
Quantity Value Units Method Reference Comment
Δcliquid-6192.2 ± 1.8kJ/molCcbKozina, Aleshina, et al., 1975Corresponding Δfliquid = -29.5 kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
BS - Robert L. Brown and Stephen E. Stein
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil446.5KN/AArbusov and Michailov, 1930Uncertainty assigned by TRC = 2. K; TRC
Tboil443.KN/ADupont, 1924Uncertainty assigned by TRC = 4. K; TRC
Tboil442.KN/ASimonsen, 1920Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Δvap48.3 ± 3.1kJ/molVKozina, Aleshina, et al., 1975ALS
Δvap48.5kJ/molN/AKozina, Aleshina, et al., 1975DRB

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
441.70.940Aldrich Chemical Company Inc., 1990BS

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

Mass spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin RESEARCH LABORATORY, STATE ALCOHOL MONOPOLY ALKO, HELSINKI, FINLAND; IRMA NYKANEN ET AL
NIST MS number 77623

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kozina, Aleshina, et al., 1975
Kozina, M.P.; Aleshina, V.A.; Gal'chenko, G.L.; Buinova, E.F.; Bardyshev, I.I., Enthalpies of combustion of 3- and 2-carenes, Vestsi Akad. Nauk. BSSR, Ser. Khim. Nauk., 1975, 14-17. [all data]

Arbusov and Michailov, 1930
Arbusov, B.; Michailov, B.M., J. Prakt. Chem., 1930, 127, 1. [all data]

Dupont, 1924
Dupont, G., Ann. Chim. (Paris), 1924, 1, 184-274. [all data]

Simonsen, 1920
Simonsen, J.L., J. Chem. Soc., 1920, 117, 570. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References