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Iron pentacarbonyl


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C8H7O2- + Iron pentacarbonyl = (C8H7O2- bullet Iron pentacarbonyl)

By formula: C8H7O2- + C5FeO5 = (C8H7O2- bullet C5FeO5)

Quantity Value Units Method Reference Comment
Deltar188. ± 25.kJ/molIMRBLane, Sallans, et al., 1985gas phase
Quantity Value Units Method Reference Comment
Deltar149. ± 25.kJ/molIMRBLane, Sallans, et al., 1985gas phase

Chlorine anion + Iron pentacarbonyl = (Chlorine anion bullet Iron pentacarbonyl)

By formula: Cl- + C5FeO5 = (Cl- bullet C5FeO5)

Quantity Value Units Method Reference Comment
Deltar58. ± 13.kJ/molIMRBLane, Sallans, et al., 1985gas phase
Quantity Value Units Method Reference Comment
Deltar33. ± 13.kJ/molIMRBLane, Sallans, et al., 1985gas phase

Fluorine anion + Iron pentacarbonyl = (Fluorine anion bullet Iron pentacarbonyl)

By formula: F- + C5FeO5 = (F- bullet C5FeO5)

Quantity Value Units Method Reference Comment
Deltar171. ± 8.4kJ/molIMRELane, Sallans, et al., 1985gas phase
Quantity Value Units Method Reference Comment
Deltar144. ± 8.4kJ/molIMRELane, Sallans, et al., 1985gas phase

Hydrogen anion + Iron pentacarbonyl = (Hydrogen anion bullet Iron pentacarbonyl)

By formula: H- + C5FeO5 = (H- bullet C5FeO5)

Quantity Value Units Method Reference Comment
Deltar235. ± 13.kJ/molIMRBLane, Sallans, et al., 1985gas phase

HO- + Iron pentacarbonyl = (HO- bullet Iron pentacarbonyl)

By formula: HO- + C5FeO5 = (HO- bullet C5FeO5)

Quantity Value Units Method Reference Comment
Deltar254. ± 14.kJ/molIMRESunderlin and Squires, 1993gas phase; HO- transfer equilibrium to SO2. Structure thought ot be (CO)4Fe-CO2H
Deltar237. ± 17.kJ/molIMRBLane, Sallans, et al., 1985gas phase
Quantity Value Units Method Reference Comment
Deltar196. ± 17.kJ/molIMRBLane, Sallans, et al., 1985gas phase

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lane, Sallans, et al., 1985
Lane, K.R.; Sallans, L.; Squires, R.R., Anion affinities of transition metal carbonyls. A thermochemical correlation for iron tetracarbonyl acyl negative ions, J. Am. Chem. Soc., 1985, 107, 5369. [all data]

Sunderlin and Squires, 1993
Sunderlin, L.S.; Squires, R.R., Energetics and Mechanism of the Thermal Decarboxylation of (CO)4FeCOOH- in the Gas Phase, J. Am. Chem. Soc., 1993, 115, 1, 337, https://doi.org/10.1021/ja00054a048 . [all data]


Notes

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