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Tellurium monoxide


Constants of diatomic molecules

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through November, 1977

Symbols used in the table of constants
SymbolMeaning
State electronic state and / or symmetry symbol
Te minimum electronic energy (cm-1)
ωe vibrational constant – first term (cm-1)
ωexe vibrational constant – second term (cm-1)
ωeye vibrational constant – third term (cm-1)
Be rotational constant in equilibrium position (cm-1)
αe rotational constant – first term (cm-1)
γe rotation-vibration interaction constant (cm-1)
De centrifugal distortion constant (cm-1)
βe rotational constant – first term, centrifugal force (cm-1)
re internuclear distance (Å)
Trans. observed transition(s) corresponding to electronic state
ν00 position of 0-0 band (units noted in table)
Diatomic constants for 130Te16O
StateTeomegaeomegaexeomegaeyeBealphaegammaeDebetaereTrans.nu00
Fragment of an absorption system in the region 32700 - 36000 cm-1; it is not certain that these bands are due to TeO.
Shin-Piaw, 1938
A2 1 [28719] 1   [0.2771] 2 (0.004)  [2E-7]  [2.067] A2 rarrow X2 R 27641.95 Z
missing citation; missing citation
A1 0+ (28212) [444.95] Z 3  0.2760 2 4 0.0052  4E-7  2.071 A1 lrarrow X1 R 28037.04 Z
missing citation; missing citation
Unclassified emission bands 16000 - 20000 cm-1.
Haranath, Rao, et al., 1959
StateTeomegaeomegaexeomegaeyeBealphaegammaeDebetaereTrans.nu00
X2 1 679 5 798.06 Z 4.00  0.3564 6 0.00236  3E-7  1.8224  
X1 0+ 0 797.11 Z 4.00  0.3554 0.00237  2.7E-7  1.8250  

Notes

1 Chandler, Hurst, et al., 1965 give, without details, G(1/2) ~ 458 for 128Te0. Haranath, Rao, et al., 1959, by contrast, suggest omegae = 408, omegaexe = 4.0. According to Chandler, Hurst, et al., 1965 this state is predissociated between v=2 and 3.
2Extensive perturbations.
3DeltaG(3/2)=409.9, DeltaG(5/2)=393.4, DeltaG(7/2)=364.53. From v=3 to 10 the vibrational intervals are quite well represented by omegae(3 leq v leq 10) = 410.71, omegaexe(3 leq v leq 10) = 5.772; large deviations occur below and above these limits. Vibrational levels observed to v = 15. The v' numbering has been established from isotope shifts Chandler, Hurst, et al., 1965 and has been increased by +3 units compared to the numbering used by Shin-Piaw, 1938 and Haranath, Rao, et al., 1959.
4Absorption lines become diffuse above J' ~ 42 and 14 in v'=9 and 10, respectively; the highest observed level in emission is v'=9. The predissociation limit (~31450 cm-1) is assumed to correspond to normal atomic products.
5Estimated Barrow and Hitchings, 1972 from the magnitude of their Omega-type doubling in X2 1 (see 6).
6B(1+) - B(1-) ~ +0.00066 Barrow and Hitchings, 1972.
7From the predissociation in A1 0+ (see 4).
8From the photoelectron spectrum Potts and Williams, 1976.
9D00(TeO) + I.P.(Te) - I.P.(TeO).

References

Go To: Top, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Shin-Piaw, 1938
Shin-Piaw, C., Spectres de bandes du selenium, du tellure et de leurs oxydes dans l'ultra-violet, Ann. Phys. (Paris), 1938, 10, 173-175. [all data]

Haranath, Rao, et al., 1959
Haranath, P.B.V.; Rao, P.T.; Sivaramamurty, V., New emission spectrum of the TeO molecule, Z. Phys., 1959, 155, 507. [all data]

Chandler, Hurst, et al., 1965
Chandler, G.G.; Hurst, H.J.; Barrow, R.F., Rotational analysis of the A-X system of tellurium monoxide, Proc. Phys. Soc. London, 1965, 86, 105. [all data]

Barrow and Hitchings, 1972
Barrow, R.F.; Hitchings, M.R., The «OMEGA»=1,0+ separation in the 3«SIGMA»- ground state of gaseous TeO, J. Phys. B:, 1972, 5, 132. [all data]

Potts and Williams, 1976
Potts, A.W.; Williams, T.A., The He I photoelectron spectrum of TeO, Chem. Phys. Lett., 1976, 42, 550. [all data]


Notes

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