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gallium triiodide

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Deltasub100.5 ± 2.0kJ/molTEBrunetti, Piacente, et al., 2010Based on data from 345. - 401. K.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Gallium trimethyl (l) + 3Iodine (cr) = GaI3 (cr) + 3Methane, iodo- (l)

By formula: C3H9Ga (l) + 3I2 (cr) = GaI3 (cr) + 3CH3I (l)

Quantity Value Units Method Reference Comment
Deltar-200.0 ± 8.4kJ/molRSCFowell and Mortimer, 1958Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
9.40PEDehmer, Berkowitz, et al., 1974 
9.51PEBarker, Lappert, et al., 1975Vertical value
9.51PELappert, Pedley, et al., 1974Vertical value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brunetti, Piacente, et al., 2010
Brunetti, Bruno; Piacente, Vincenzo; Scardala, Paolo, Vapor Pressures of Gallium Trifluoride, Trichloride, and Triiodide and Their Standard Sublimation Enthalpies, J. Chem. Eng. Data, 2010, 55, 1, 98-102, https://doi.org/10.1021/je900276q . [all data]

Fowell and Mortimer, 1958
Fowell, P.A.; Mortimer, C.T., J. Chem. Soc., 1958, 3734.. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Dehmer, Berkowitz, et al., 1974
Dehmer, J.L.; Berkowitz, J.; Cusachs, L.C.; Aldrich, H.S., Photoelectron spectroscopy of high temperature vapors. V. HeI spectra of GaX3 and InX3 (X = Cl, Br, I), J. Chem. Phys., 1974, 61, 594. [all data]

Barker, Lappert, et al., 1975
Barker, G.K.; Lappert, M.F.; Pedley, J.B.; Sharp, G.J.; Westwood, N.P.C., Bonding studies of boron and the group 3-5 elements. Part XV. He(I) photoelectron spectra of monomeric group 3 tri-halide, trimethyl, and mixed halogenomethyl species, J. Chem. Soc. Dalton Trans., 1975, 1765. [all data]

Lappert, Pedley, et al., 1974
Lappert, M.F.; Pedley, J.B.; Sharp, G.J.; Westwood, N.P.C., Bonding studies of compounds of boron and the Group III and IV elements. XII. Variable temperature HeI photoelectron spectra of Group III halides, 2MX3<=>M2X6(M=Al or Ga, X=Cl, Br, or I), J. Electron Spectrosc. Relat. Phenom., 1974, 3, 237. [all data]


Notes

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