Nitrosyl bromide
- Formula: BrNO
- Molecular weight: 109.910
- IUPAC Standard InChI: InChI=1S/BrNO/c1-2-3
- IUPAC Standard InChIKey: BMNDJWSIKZECMH-UHFFFAOYSA-N
- CAS Registry Number: 13444-87-6
- Chemical structure:
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Gas phase thermochemistry data
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | 82.13 | kJ/mol | Review | Chase, 1998 | Data last reviewed in December, 1966 |
| Quantity | Value | Units | Method | Reference | Comment |
| S°gas,1 bar | 273.53 | J/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1966 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
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| Temperature (K) | 298. - 1200. | 1200. - 6000. |
|---|---|---|
| A | 40.02214 | 56.99738 |
| B | 25.24977 | 0.644436 |
| C | -13.32508 | -0.126207 |
| D | 2.411069 | 0.008519 |
| E | -0.084503 | -3.416262 |
| F | 68.90713 | 57.11746 |
| G | 314.5276 | 331.6812 |
| H | 82.13192 | 82.13192 |
| Reference | Chase, 1998 | Chase, 1998 |
| Comment | Data last reviewed in December, 1966 | Data last reviewed in December, 1966 |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
(l) +
(cr) = C9H19BrMg (solution)
By formula: BrNO (l) + Mg (cr) = C9H19BrMg (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -231.0 ± 4.4 | kJ/mol | RSC | Holm, 1981 | solvent: Diethyl ether; Due to the possibility of side reactions, the enthalpy of reaction was not considered to be sufficiently reliable for deriving the enthalpy of formation of the Grignard reagent Holm, 1981 |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| IE (evaluated) | 10.19 ± 0.05 | eV | N/A | N/A | L |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 10.20 ± 0.05 | PE | Alderdice and Dixon, 1977 | LLK |
| 10.17 ± 0.03 | PE | Frost, Lee, et al., 1975 | LLK |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Holm, 1981
Holm, T.,
J. Chem. Soc., Perkin Trans. II, 1981, 464.. [all data]
Alderdice and Dixon, 1977
Alderdice, D.S.; Dixon, R.N.,
Photoelectron spectra of nitrosyl halides,
J. Chem. Soc. Faraday Trans. 2, 1977, 73, 245. [all data]
Frost, Lee, et al., 1975
Frost, D.C.; Lee, S.T.; McDowell, C.A.; Westwood, N.P.C.,
Photoelectron spectroscopic studies of some nitrosyl and nitryl halides nitric acid,
J. Electron Spectrosc. Relat. Phenom., 1975, 7, 331. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
IE (evaluated) Recommended ionization energy S°gas,1 bar Entropy of gas at standard conditions (1 bar) ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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