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2-Butene, 1-chloro-2-methyl-

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Reaction thermochemistry data

Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

1-Butene, 3-chloro-2-methyl- = 2-Butene, 1-chloro-2-methyl-

By formula: C5H9Cl = C5H9Cl

Quantity Value Units Method Reference Comment
Deltar-0.48 ± 0.32kcal/molEqkMeged, Levanova, et al., 1978gas phase; UV Irradiation

Butane, 1,2-dichloro-2-methyl- = 2-Butene, 1-chloro-2-methyl- + Hydrogen chloride

By formula: C5H10Cl2 = C5H9Cl + HCl

Quantity Value Units Method Reference Comment
Deltar16.3 ± 1.0kcal/molEqkMeged, Levanova, et al., 1980gas phase

Mass spectrum (electron ionization)

Go To: Top, Reaction thermochemistry data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 159135

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Gas Chromatography

Go To: Top, Reaction thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryOV-101755.Zenkevich, 200525. m/0.20 mm/0.10 «mu»m, N2/He, 6. K/min; Tstart: 50. C; Tend: 250. C

References

Go To: Top, Reaction thermochemistry data, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meged, Levanova, et al., 1978
Meged, V.M.; Levanova, S.V.; Shevtsova, L.A.; Rozhnov, A.M.; Kudryavtseva, T.A., The allyl rearrangement of chloromethylbutenes, Russ. J. Phys. Chem. (Engl. Transl.), 1978, 52, 286. [all data]

Meged, Levanova, et al., 1980
Meged, V.M.; Levanova, S.V.; Rozhnov, A.M., Dehydrohalogenation of dihalomethylbutanes. 2., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1980, 23, 149-151. [all data]

Zenkevich, 2005
Zenkevich, I.G., Experimentally measured retention indices., 2005. [all data]


Notes

Go To: Top, Reaction thermochemistry data, Mass spectrum (electron ionization), Gas Chromatography, References