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Copper, bis(2,4-pentanedionato-O,O')-, (SP-4-1)-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
7.2PEKitagawa, Morishima, et al., 1983LBLHLM
8.31 ± 0.05EIReichert and Westmore, 1969RDSH
7.75 ± 0.05EIHoltzclaw, Lintvedt, et al., 1969RDSH
8.35PEShcheka and Vovna, 1992Vertical value; LL
7.66PEKitagawa, Morishima, et al., 1983Vertical value; LBLHLM
8.35PECauletti, Furlani, et al., 1980Vertical value; LLK
8.20PEBrittain and Disch, 1975Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C5H7O2Cu+13.1 ± 0.2?EIReichert and Westmore, 1969RDSH
C9H11O4Cu+10.9 ± 0.1?EIReichert and Westmore, 1969RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kitagawa, Morishima, et al., 1983
Kitagawa, S.; Morishima, I.; Yoshikawa, K., UV photoelectron spectra of some transition metal(II)aAcetylacetonates, Polyhedron, 1983, 2, 43. [all data]

Reichert and Westmore, 1969
Reichert, C.; Westmore, J.B., Mass spectral studies of metal chelates. IV.Mass spectra, appearance potentials, and coordinate bond energies of bis(acetylacetonate)metal(II) complexes of the first transition series, Inorg. Chem., 1969, 8, 1012. [all data]

Holtzclaw, Lintvedt, et al., 1969
Holtzclaw, H.F., Jr.; Lintvedt, R.L.; Baumgarten, H.E.; Parker, R.G.; Bursey, M.M.; Rogerson, P.F., Mass spectra of metal chelates. I. Substituent effects on ionization potentials and fragmentation patterns of some 1-methyl-3-alkyl-1,3-dione-copper(II) chelates, J. Am. Chem. Soc., 1969, 91, 3774. [all data]

Shcheka and Vovna, 1992
Shcheka, O.L.; Vovna, V.I., Electronic structure of some copper(II) and iron(III) -diketonates, J. Electron Spectrosc. Relat. Phenom., 1992, 60, 211. [all data]

Cauletti, Furlani, et al., 1980
Cauletti, C.; Furlani, C.; Storto, G., Coordinative bond d-shell ionisations in the UV photoelectron spectra of bis({beta}-diketonato) cobalt (II) copper (II) complexes, their thio analogues, J. Electron Spectrosc. Relat. Phenom., 1980, 18, 329. [all data]

Brittain and Disch, 1975
Brittain, H.G.; Disch, R.L., The He(I) photoelectron spectra of some bivalent transition metal «beta»-diketonate complexes*, J. Electron Spectrosc. Relat. Phenom., 1975, 7, 475. [all data]


Notes

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