Reaction data
+ =
Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
ΔrH° (kJ/mol) | Method | Reference | Comment |
---|---|---|---|
-125.2 ± 0.5 | Chyd | Rogers and Dejroongruang, 1988 | liquid phase; solvent: Hydrocarbone; ALS |
-127. ± 0.4 | Chyd | Roth and Lennartz, 1980 | liquid phase; solvent: Cyclohexane; ALS |
-124.3 ± 1.5 | Chyd | Rogers and Skanupong, 1974 | liquid phase; solvent: Hexane; ALS |
-124.3 ± 0.54 | Chyd | Williams, 1942 | liquid phase; solvent: Acetic acid; Reanalyzed by Cox and Pilcher, 1970, Original value = -125. ± 13. kJ/mol; At 302 K; ALS |
-123. | Chyd | Bent, Cuthbertson, et al., 1936 | liquid phase; ALS |
-125.1 ± 0.3 | Chyd | Kistiakowsky, Ruhoff, et al., 1936 | gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -126.1 ± 0.3 kJ/mol; At 355 K; ALS |
References
Go To: Top, Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Rogers and Dejroongruang, 1988
Rogers, D.W.; Dejroongruang, K.,
Enthalpies of hydrogenation of the n-heptenes and the methylhexenes,
J. Chem. Thermodyn., 1988, 20, 675-680. [all data]
Roth and Lennartz, 1980
Roth, W.R.; Lennartz, H.W.,
Heats of hydrogenation. I. Determination of heats of hydrogenation with an isothermal titration calorimeter,
Chem. Ber., 1980, 113, 1806-1817. [all data]
Rogers and Skanupong, 1974
Rogers, D.W.; Skanupong, S.,
Heats of hydrogenation of sixteen terminal monoolefins. The alternating effect,
J. Phys. Chem., 1974, 78, 2569-2572. [all data]
Williams, 1942
Williams, R.B.,
Heats of catalytic hydrogenation in solution. I. Apparatus, technique, and the heats of hydrogenation of certain pairs of stereoisomers,
J. Am. Chem. Soc., 1942, 64, 1395-1404. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Bent, Cuthbertson, et al., 1936
Bent, H.E.; Cuthbertson, G.R.; Dorfman, M.; Leary, R.E.,
Single bond energies. I. The C-C bond in hexaphenylethane,
J. Am. Chem. Soc., 1936, 58, 165-170. [all data]
Kistiakowsky, Ruhoff, et al., 1936
Kistiakowsky, G.B.; Ruhoff, J.R.; Smith, H.A.; Vaughan, W.E.,
Heats of organic reactions. III. Hydrogenation of some higher olefins,
J. Am. Chem. Soc., 1936, 58, 137-145. [all data]
Notes
Go To: Top, Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.), References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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