1,4-Bis(trimethylsilyl)benzene
- Formula: C12H22Si2
- Molecular weight: 222.4741
- IUPAC Standard InChI: InChI=1S/C12H22Si2/c1-13(2,3)11-7-9-12(10-8-11)14(4,5)6/h7-10H,1-6H3
- IUPAC Standard InChIKey: NVRBTKMAZQNKPX-UHFFFAOYSA-N
- CAS Registry Number: 13183-70-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Silane, 1,4-phenylenebis[trimethyl-; Silane, p-phenylenebis[trimethyl-; p-Bis(trimethylsilyl)benzene; Benzene, p-bis(trimethylsilyl)-; p-Phenylenebis(trimethylsilane); Trimethyl[4-(trimethylsilyl)phenyl]silane
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.45 | PE | Traven', Redchenko, et al., 1982 | LBLHLM |
| 8.25 | EI | Bock and Alt, 1970 | RDSH |
| 8.78 | PE | Traven', Redchenko, et al., 1982 | Vertical value; LBLHLM |
| 8.7 | PE | Kaim, Tesmann, et al., 1980 | Vertical value; LLK |
| 8.98 | PE | Limouzin and Maire, 1976 | Vertical value; LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Traven', Redchenko, et al., 1982
Traven', V.F.; Redchenko, V.V.; Stepanov, B.I.,
Parameterization of quantum-chemical calculations of organic compounds of silicon by means of photoelectron spectroscopy and the electronic spectroscopy of ctc,
J. Gen. Chem. USSR, 1982, 52, 2015, In original 2262. [all data]
Bock and Alt, 1970
Bock, H.; Alt, H.,
d-Orbital effects in silicon substituted π-electron systems. XXIV. Charge-transfer studies of silyl- and alkylbenzenes,
J. Am. Chem. Soc., 1970, 92, 1569. [all data]
Kaim, Tesmann, et al., 1980
Kaim, W.; Tesmann, H.; Bock, H.,
Me3C-, Me3Si-, Me3Ge-, Me3Sn- und Me3Pb-substituierte benzol- und naphthalin-derivate und ihre radikalanionen,
Chem. Ber., 1980, 113, 3221. [all data]
Limouzin and Maire, 1976
Limouzin, Y.; Maire, J.C.,
Spectres photo-electroniques des composes organometalliques,
J. Organomet. Chem., 1976, 105, 179. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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