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molybdenum trioxide

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
3.170 ± 0.020LPESYoder, Maze, et al., 2005B
2.85 ± 0.21R-ARudnyi, Vovk, et al., 1989Multi-parameter fit to many IMRE, Ion-ion Eq. «DELTA»Hf(A-) at 0 K; value altered from reference due to conversion from electron convention to ion convention; B
3.10 ± 0.45R-AMiller, 1979H + HMoO4- <=> H2O + MoO3-; B

Ionization energy determinations

IE (eV) Method Reference Comment
11.8 ± 0.5EIYamdagni, Pupp, et al., 1970RDSH
12.2 ± 0.5EIPupp, Yamdagni, et al., 1969RDSH
11.8EIDrowart, Exsteen, et al., 1964RDSH
12.0 ± 0.6EIDeMaria, Burns, et al., 1960RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Yoder, Maze, et al., 2005
Yoder, B.L.; Maze, J.T.; Raghavachari, K.; Jarrold, C.C., Structures of Mo2Oy- and Mo2Oy (y=2, 3, and 4) studied by anion photoelectron spectroscopy and density functional theory calculations, J. Chem. Phys., 2005, 122, 9, 094313, https://doi.org/10.1063/1.1853379 . [all data]

Rudnyi, Vovk, et al., 1989
Rudnyi, E.B.; Vovk, O.M.; Kaibicheva, E.A.; Sidorov, L.N., Formation Enthalpies of Oxygen Containing Anions of Group VI Elements in the Gas Phase and the Electron Affinities of CrO3, MoO3, and WO3, J. Chem. Thermodyn., 1989, 21, 3, 247, https://doi.org/10.1016/0021-9614(89)90014-1 . [all data]

Miller, 1979
Miller, W.J., The use of flames as media for the study of in-molecule thermochemistry in characterization of high temperature vapors and gases, NBS Spec. Publ. U.S., 1979, 561, 443. [all data]

Yamdagni, Pupp, et al., 1970
Yamdagni, R.; Pupp, C.; Porter, R.F., Mass spectrometric study of the evaporation of lithium and sodium molybdates and tungstates, J. Inorg. Nucl. Chem., 1970, 32, 3509. [all data]

Pupp, Yamdagni, et al., 1969
Pupp, C.; Yamdagni, R.; Porter, R.F., Mass spectrometric study of the evaporation of BaMoO4 and BaWO4, J. Inorg. Nucl. Chem., 1969, 31, 2021. [all data]

Drowart, Exsteen, et al., 1964
Drowart, J.; Exsteen, G.; Verhaegen, G., Mass spectrometric determination of the dissociation energy of the molecules MgO, CaO, SrO and Sr2O, J. Chem. Soc. Faraday Trans., 1964, 60, 1920. [all data]

DeMaria, Burns, et al., 1960
DeMaria, G.; Burns, R.P.; Drowart, J.; Inghram, M.G., Mass spectrometric study of gaseous molybdenum, tungsten, and uranium oxides, J. Chem. Phys., 1960, 32, 1373. [all data]


Notes

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