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manganese dioxide


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
2.060 ± 0.030LPESGutsev, Rao, et al., 2000 
3.03 ± 0.34R-ARudnyi, Kaibicheva, et al., 1993Data at 0 K. See also Pramann and Rademann, 1999; value altered from reference due to conversion from electron convention to ion convention
<0.73 ± 0.41IMRBFokkens, Gregor, et al., 1991EA: < MnO3-

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gutsev, Rao, et al., 2000
Gutsev, G.L.; Rao, B.K.; Jena, P.; Li, X.; Wang, L.S., Experimental and theoretical study of the photoelectron spectra of MnOx-(x=1-3) clusters, J. Chem. Phys., 2000, 113, 4, 1473-1483, https://doi.org/10.1063/1.481964 . [all data]

Rudnyi, Kaibicheva, et al., 1993
Rudnyi, E.B.; Kaibicheva, E.A.; Sidorov, L.N., Enthalpies of Formation of the Negative Ions MnO2-, MnO3- and MnO4- as Determined by the Ion/Molecule Equilibrium Method, Rapid Commun. Mass Spectrom., 1993, 7, 9, 800, https://doi.org/10.1002/rcm.1290070904 . [all data]

Pramann and Rademann, 1999
Pramann, A.; Rademann, K., Mass-spectrometric study of formation and stability of manganese and manganese oxide cluster anions, Int. J. Mass Spectrom., 1999, 187, 673-683, https://doi.org/10.1016/S1387-3806(98)14197-0 . [all data]

Fokkens, Gregor, et al., 1991
Fokkens, R.H.; Gregor, I.K.; Nibbering, N.M.M., Gas-Phase Chemistry of Metal Oxide Anions - The Reactions of Dioxomanganate(III), MnO2- and Trioxomanganate(V), MnO3- Ions with Aliphatic Al, Rapid Commun. Mass Spectrom., 1991, 5, 8, 368, https://doi.org/10.1002/rcm.1290050808 . [all data]


Notes

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