Acetamide, N-hydroxy-N-methyl
- Formula: C3H7NO2
- Molecular weight: 89.0932
- IUPAC Standard InChI: InChI=1S/C3H7NO2/c1-3(5)4(2)6/h6H,1-2H3
- IUPAC Standard InChIKey: BJPJMTMWIVUMAK-UHFFFAOYSA-N
- CAS Registry Number: 13115-24-7
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
Data compiled as indicated in comments:
B - John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| Proton affinity (review) | 876.2 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
| Quantity | Value | Units | Method | Reference | Comment |
| Gas basicity | 845.3 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
De-protonation reactions
C3H6NO2- + =
By formula: C3H6NO2- + H+ = C3H7NO2
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1482. ± 9.6 | kJ/mol | G+TS | Decouzon, Exner, et al., 1990 | gas phase; Acid: N-methyl acetohydroxamic acid; B |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1451. ± 8.4 | kJ/mol | IMRE | Decouzon, Exner, et al., 1990 | gas phase; Acid: N-methyl acetohydroxamic acid; B |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Decouzon, Exner, et al., 1990
Decouzon, M.; Exner, O.; Gal, J.-F.; Maria, P.-C.,
The Gas-Phase Acidity and the Acidic Site of Acetohydroxamic Acid: an FT-ICR Study,
J. Org. Chem., 1990, 55, 13, 3980, https://doi.org/10.1021/jo00300a007
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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