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SrBH4


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 14422.56 gas B-X 651 718 Pianalto, Bopegedera, et al., 1991
Dick, Sheridan, et al., 2007


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 Sr..BH4 stretch 408 ± 10 gas LF Pianalto, Bopegedera, et al., 1991

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 13723 ± 10 gas A-X 707 772 Pianalto, Bopegedera, et al., 1991


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 Sr..BH4 stretch 404 ± 10 gas LF Pianalto, Bopegedera, et al., 1991

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 Sr..BH4 stretch 388 ± 10 gas LF Pianalto, Bopegedera, et al., 1991

Additional references: Jacox, 1994, page 306

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pianalto, Bopegedera, et al., 1991
Pianalto, F.S.; Bopegedera, A.M.R.P.; Fernando, W.T.M.L.; Hailey, R.; O'Brien, L.C.; Brazier, C.R.; Keller, P.C.; Bernath, P.F., Gas-phase inorganic chemistry: laser spectroscopy of calcium and strontium monoborohydrides, J. Am. Chem. Soc., 1991, 112, 22, 7900, https://doi.org/10.1021/ja00178a008 . [all data]

Dick, Sheridan, et al., 2007
Dick, M.J.; Sheridan, P.M.; Wang, J.-G.; Bernath, P.F., High resolution laser excitation spectroscopy of the B [sup 2]E-X [sup 2]A[sub 1] transitions of calcium and strontium monoborohydride, J. Chem. Phys., 2007, 126, 16, 164311, https://doi.org/10.1063/1.2723097 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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