tris(η5-cyclopenta-2,4-dien-1-yl)yttrium
- Formula: C15H15Y
- Molecular weight: 284.1855
- CAS Registry Number: 1294-07-1
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | 66.6 ± 6.2 | kJ/mol | Review | Martinho Simões |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°solid | -45.1 ± 5.1 | kJ/mol | Review | Martinho Simões | MS |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°solid | -8953.8 ± 4.2 | kJ/mol | CC-SB | Devyatykh, Rabinovich, et al., 1974 | Please also see Pedley and Rylance, 1977 and Tel'noi and Rabinovich, 1977.; MS |
| Quantity | Value | Units | Method | Reference | Comment |
| S°solid,1 bar | 301.6 | J/mol*K | N/A | Sheiman, Kamelova, et al., 1982 | DH |
Constant pressure heat capacity of solid
| Cp,solid (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 289.0 | 298.15 | Sheiman, Kamelova, et al., 1982 | T = 4.5 to 300 K.; DH |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔsubH° | 111.7 ± 3.5 | kJ/mol | N/A | Pilcher and Skinner, 1983 | See also Devyatykh, Rabinovitch, et al., 1974.; AC |
| ΔsubH° | 111.7 ± 3.5 | kJ/mol | CC-SB | Devyatykh, Borisov, et al., 1973 | MS |
Temperature of phase transition
| Ttrs (K) | Initial Phase | Final Phase | Reference | Comment |
|---|---|---|---|---|
| 265. - 280. | crystaline, II, Order | crystaline, I, disorder transition | Sheiman, Kamelova, et al., 1982 | DH |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Devyatykh, Rabinovich, et al., 1974
Devyatykh, C.G.; Rabinovich, I.B.; Tel'noi, V.I.; Borisov, G.K.; Zyazina, L.F.,
Dokl. Akad. Nauk SSSR, 1974, 217, 609. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B.,
Russ. Chem. Rev., 1977, 46, 689. [all data]
Sheiman, Kamelova, et al., 1982
Sheiman, M.S.; Kamelova, G.P.; Borisov, G.K.,
Heat capacity and thermodynamic functions of tricyclopentadienyl yttrium, 1982, Termodin. [all data]
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A.,
Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2
. [all data]
Devyatykh, Rabinovitch, et al., 1974
Devyatykh, C.G.; Rabinovitch, I.B.; Tel'noi, V.I.; Borisov, G.K.; Zyazina, L.F.,
Dokl. Akad. Nauk SSSR, 1974, 217, 673. [all data]
Devyatykh, Borisov, et al., 1973
Devyatykh, G.G.; Borisov, G.K.; Zyuzina, L.F.; Krasnova, S.G.,
Dokl. Akad. Nauk SSSR, 1973, 212, 1, 127. [all data]
Notes
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- Symbols used in this document:
Cp,solid Constant pressure heat capacity of solid S°solid,1 bar Entropy of solid at standard conditions (1 bar) Ttrs Temperature of phase transition ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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