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tris(«eta»5-cyclopenta-2,4-dien-1-yl)yttrium


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas66.6 ± 6.2kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid-45.1 ± 5.1kJ/molReviewMartinho SimõesMS
Quantity Value Units Method Reference Comment
Deltacsolid-8953.8 ± 4.2kJ/molCC-SBDevyatykh, Rabinovich, et al., 1974Please also see Pedley and Rylance, 1977 and Tel'noi and Rabinovich, 1977.; MS
Quantity Value Units Method Reference Comment
solid,1 bar301.6J/mol*KN/ASheiman, Kamelova, et al., 1982DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
289.0298.15Sheiman, Kamelova, et al., 1982T = 4.5 to 300 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltasub111.7 ± 3.5kJ/molN/APilcher and Skinner, 1983See also Devyatykh, Rabinovitch, et al., 1974.; AC
Deltasub111.7 ± 3.5kJ/molCC-SBDevyatykh, Borisov, et al., 1973MS

Temperature of phase transition

Ttrs (K) Initial Phase Final Phase Reference Comment
265. - 280.crystaline, II, Ordercrystaline, I, disorder transitionSheiman, Kamelova, et al., 1982DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Devyatykh, Rabinovich, et al., 1974
Devyatykh, C.G.; Rabinovich, I.B.; Tel'noi, V.I.; Borisov, G.K.; Zyazina, L.F., Dokl. Akad. Nauk SSSR, 1974, 217, 609. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B., Russ. Chem. Rev., 1977, 46, 689. [all data]

Sheiman, Kamelova, et al., 1982
Sheiman, M.S.; Kamelova, G.P.; Borisov, G.K., Heat capacity and thermodynamic functions of tricyclopentadienyl yttrium, 1982, Termodin. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Devyatykh, Rabinovitch, et al., 1974
Devyatykh, C.G.; Rabinovitch, I.B.; Tel'noi, V.I.; Borisov, G.K.; Zyazina, L.F., Dokl. Akad. Nauk SSSR, 1974, 217, 673. [all data]

Devyatykh, Borisov, et al., 1973
Devyatykh, G.G.; Borisov, G.K.; Zyuzina, L.F.; Krasnova, S.G., Dokl. Akad. Nauk SSSR, 1973, 212, 1, 127. [all data]


Notes

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