Aluminum oxide anion
- Formula: AlO-
- Molecular weight: 42.9815
- CAS Registry Number: 12758-12-2
- Information on this page:
- Other data available:
- Options:
Gas phase thermochemistry data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| S°gas,1 bar | 50.848 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1979 |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
AlO- + = HAlO
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 367.9 ± 9.6 | kcal/mol | D-EA | Desai, Wu, et al., 1996 | gas phase |
| ΔrH° | 359.6 ± 4.1 | kcal/mol | G+TS | Damrauer, Krempp, et al., 1991 | gas phase; Between CF3CH2OH, pyrrole. Calculations imply that the acid is AlOH, not HAlO |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 360.7 ± 9.7 | kcal/mol | H-TS | Desai, Wu, et al., 1996 | gas phase |
| ΔrG° | 352.5 ± 4.0 | kcal/mol | IMRB | Damrauer, Krempp, et al., 1991 | gas phase; Between CF3CH2OH, pyrrole. Calculations imply that the acid is AlOH, not HAlO |
(AlO- • 4294967295) +
= AlO-
By formula: (AlO- • 4294967295Al) + Al = AlO-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 148.6 ± 6.4 | kcal/mol | N/A | Desai, Wu, et al., 1996 | gas phase |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Desai, Wu, et al., 1996
Desai, S.R.; Wu, H.; Wang, L.-S.,
Vibrationally Resolved Photoelectron Spectroscopy of AlO- and AlO2-,
Int. J. Mass Spectrom. Ion Proc., 1996, 159, 1-3, 75, https://doi.org/10.1016/S0168-1176(96)04443-6
. [all data]
Damrauer, Krempp, et al., 1991
Damrauer, R.; Krempp, M.; Schmidt, M.W.; Gordon, M.S.,
Gas-Phase Chemistry of the Dimethylaluminum Oxide Ion and Related Aluminum Oxide Ions - Comparison of Reactivity with Siloxide Ions,
J. Am. Chem. Soc., 1991, 113, 7, 2393, https://doi.org/10.1021/ja00007a007
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.