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tris(«eta»5-2,4-cyclopentadien-1-yl)thulium


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas61.8 ± 6.2kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafsolid-49.5 ± 5.1kJ/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Deltacsolid-8941.2 ± 4.2kJ/molCC-SBDevyatykh, Rabinovich, et al., 1974Please also see Pedley and Rylance, 1977 and Tel'noi and Rabinovich, 1977.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltasub111.3 ± 3.5kJ/molN/APilcher and Skinner, 1983See also Devyatykh, Rabinovitch, et al., 1974.; AC
Deltasub111.3 ± 3.5kJ/molCC-SBDevyatykh, Borisov, et al., 1973MS

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
109.2 ± 2.1338. - 438.MEHaug, 1971See also Haug, 1971, 2.; AC

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
7.4 ± 0.1EIMuller, 1969RDSH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Devyatykh, Rabinovich, et al., 1974
Devyatykh, C.G.; Rabinovich, I.B.; Tel'noi, V.I.; Borisov, G.K.; Zyazina, L.F., Dokl. Akad. Nauk SSSR, 1974, 217, 609. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B., Russ. Chem. Rev., 1977, 46, 689. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Devyatykh, Rabinovitch, et al., 1974
Devyatykh, C.G.; Rabinovitch, I.B.; Tel'noi, V.I.; Borisov, G.K.; Zyazina, L.F., Dokl. Akad. Nauk SSSR, 1974, 217, 673. [all data]

Devyatykh, Borisov, et al., 1973
Devyatykh, G.G.; Borisov, G.K.; Zyuzina, L.F.; Krasnova, S.G., Dokl. Akad. Nauk SSSR, 1973, 212, 1, 127. [all data]

Haug, 1971
Haug, H.O., Ges. Kernforsch m.b.H. [Rep.] KFK-1283, 1971, 23. [all data]

Haug, 1971, 2
Haug, H.O., Dampfdruckmessungen von cyclopentadienylkomplexen des urans und einiger lanthaniden nach der effusionsmethode, Journal of Organometallic Chemistry, 1971, 30, 1, 53-57, https://doi.org/10.1016/S0022-328X(00)82595-4 . [all data]

Muller, 1969
Muller, J., Massenspektroskopische Untersuchungen an Tri- und Tetracyclopentadienyl-metall-Komplexen, Chem. Ber., 1969, 102, 152. [all data]


Notes

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