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Chromium, bis(«eta»6-benzene)-

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
4.9EIDevyatykh, Larin, et al., 1969RDSH
5.9 ± 0.1EIMuller and Goser, 1968RDSH
5.7 ± 0.1EIPignataro and Lossing, 1967RDSH
5.40PECabelli, Cowley, et al., 1982Vertical value; LBLHLM
5.45 ± 0.02PEGuest, Hillier, et al., 1975Vertical value; LLK
5.4 ± 0.1PEEvans, Green, et al., 1972Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C6H6+10.1?EIDevyatykh, Larin, et al., 1969RDSH
C6H6Cr+8.9?EIDevyatykh, Larin, et al., 1969RDSH
C6H6Cr+8.8 ± 0.2?EIMuller and Goser, 1968RDSH
C6H6Cr+9.2 ± 0.2?EIPignataro and Lossing, 1967RDSH
Cr+9.9 ± 0.3?EIDevyatykh, Larin, et al., 1969RDSH
Cr+10.8 ± 0.3?EIMuller and Goser, 1968RDSH


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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Devyatykh, Larin, et al., 1969
Devyatykh, G.G.; Larin, N.V.; Gaivoronskii, P.E., Mass spectrum of bis(benzene)chromiurn and the appearance potentials of ions, Zh. Obshch. Khim., 1969, 39, 1823, In original 1786. [all data]

Muller and Goser, 1968
Muller, J.; Goser, P., Massenspektroskopische Untersuchungen an Ubergangsmetall-«pi»-Komplexen mit funf-, sechs- und siebengliedrigen aromatischen Ringliganden, J. Organometal. Chem., 1968, 12, 163. [all data]

Pignataro and Lossing, 1967
Pignataro, S.; Lossing, F.P., Mass spectra and ionization potentials of C6H6CrC6H6 and C6H6Cr(CO)3, J. Organometal. Chem., 1967, 10, 531. [all data]

Cabelli, Cowley, et al., 1982
Cabelli, D.E.; Cowley, A.H.; Lagowski, J.J., The bonding in some bis(arene)chromium compounds as indicated by U. V. photoelectron zpectroscopy, Inorg. Chim. Acta, 1982, 57, 195. [all data]

Guest, Hillier, et al., 1975
Guest, M.F.; Hillier, I.H.; Higginson, B.R.; Lloyd, D.R., The electronic structure of transition metal complexes containing organic ligands II. Low energy photoelectron spectra and ab initio SCF MO calculations of dibenzene chromium and benzene chromium tricarbonyl, Mol. Phys., 1975, 29, 113. [all data]

Evans, Green, et al., 1972
Evans, S.; Green, J.C.; Jackson, S.E., He(I) photoelectron spectra of some «pi»-arene complexes, J. Chem. Soc. Faraday Trans. 2, 1972, 68, 249. [all data]


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