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Titanocene dichloride


Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

DeltasubH° (kJ/mol) Method Reference Comment
102. ± 13.N/AKISER, DILLARD, et al., 2009See also Diogo, Minas da Piedade, et al., 2001.; AC
124.4 ± 2.9MEDiogo, Minas da Piedade, et al., 2001AC
118.8 ± 2.1N/APilcher and Skinner, 1983See also Tel'noi and Rabinovich, 1977.; AC
118.8 ± 2.1CC-SBTel'noi and Rabinovich, 1977, 2Two other values for the enthalpy of sublimation have been reported: 111.7 ± 1.7 kJ/mol Balducci, Bardi, et al., 1977 and 96.2 kJ/mol Dillard and Kiser, 1969; MS
96.2CC-SBDillard and Kiser, 1969Two other values for the enthalpy of sublimation have been reported: 111.7 ± 1.7 kJ/mol Balducci, Bardi, et al., 1977 and 118.8 ± 2.1 kJ/mol Tel'noi and Rabinovich, 1977, 2; MS
96.7CC-SBDillard and Kiser, 1969Two other values for the enthalpy of sublimation have been reported: 100.4 ± 1.7 kJ/mol Balducci, Bardi, et al., 1977 and 105.0 ± 2.1 kJ/mol Kir'yanov, Tel'noi, et al., 1976; MS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

KISER, DILLARD, et al., 2009
KISER, ROBERT W.; DILLARD, JOHN G.; DUGGER, DONALD L., Mass Spectrometry of Inorganic Halides, 2009, 153-180, https://doi.org/10.1021/ba-1968-0072.ch012 . [all data]

Diogo, Minas da Piedade, et al., 2001
Diogo, Hermínio P.; Minas da Piedade, Manuel E.; Gonçalves, Jorge M.; Monte, Manuel J.S.; Ribeiro da Silva, Manuel A.V., Enthalpies of Sublimation of M(«eta»5-C5H5)2Cl2 (M = Ti, Zr, Hf, V, Nb, W) Complexes, Eur. J. Inorg. Chem., 2001, 2001, 1, 257-262, https://doi.org/10.1002/1099-0682(20011)2001:1<257::AID-EJIC257>3.0.CO;2-2 . [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B., Thermochemistry of organic compounds of transition metals, Usp. Khim., 1977, 46, 8, 1337. [all data]

Tel'noi and Rabinovich, 1977, 2
Tel'noi, V.I.; Rabinovich, I.B., Russ. Chem. Rev., 1977, 46, 689. [all data]

Balducci, Bardi, et al., 1977
Balducci, G.; Bardi, G.; de Maria, G.; Gigli, R., VII All-Union Calorimetry Conference, Moscow, 1977. [all data]

Dillard and Kiser, 1969
Dillard, J.G.; Kiser, R.W., The formation of gaseous ions from dicyclopentadienyltitanium dichloride and dicyclopentadienylzirconium dichloride upon electron impact, J. Organometal. Chem., 1969, 16, 265. [all data]

Kir'yanov, Tel'noi, et al., 1976
Kir'yanov, K.V.; Tel'noi, V.I.; Vasil'eva, G.A.; Rabinovich, I.B., Dokl. Akad. Nauk SSSR, 1976, 231, 1021. [all data]


Notes

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