Titanocene dichloride
- Formula: C10H10Cl2Ti
- Molecular weight: 248.959
- IUPAC Standard InChIKey: XKLWATAZDMHTSH-UHFFFAOYSA-L
- CAS Registry Number: 1271-19-8
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Titanium, dichlorobis(η5-2,4-cyclopentadien-1-yl)-; Titanium, dichlorodi-π-cyclopentadienyl-; bis(η5-Cyclopentadienyl)titanium dichloride; Bis(π-cyclopentadienyl)titanium dichloride; Bis(cyclopentadienyl)titanium dichloride; Dichlorobis(π-cyclopentadienyl)titanium; Dichlorobis(cyclopentadienyl)titanium; Dichlorodi-π-cyclopentadienyltitanium; Dichlorodicyclopentadienyltitanium; Dichlorotitanocene; Dicyclopentadienyldichlorotitanium; Dicyclopentadienyltitanium dichloride; Bis(π-cyclopentadienyl)dichlorotitanium; Dichlorobis(η5-cyclopentadienyl)titanium; Dichlorobis(η5-2,4-cyclopentadien-1-yl)titanium; NCI-C04502; Titanium, bis(cyclopentadienyl)dichloride-; Bis(cyclopentadienyl)dichlorotitanium; Dichlorobis(1,3-cyclopentadiene)titanium; NSC 78453; dichlorobis(η-cyclopentadienyl)titanium
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Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.)
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
ΔsubH° (kcal/mol) | Method | Reference | Comment |
---|---|---|---|
24.4 ± 3.1 | N/A | KISER, DILLARD, et al., 2009 | See also Diogo, Minas da Piedade, et al., 2001.; AC |
29.73 ± 0.69 | ME | Diogo, Minas da Piedade, et al., 2001 | AC |
28.39 ± 0.50 | N/A | Pilcher and Skinner, 1983 | See also Tel'noi and Rabinovich, 1977.; AC |
28.39 ± 0.50 | CC-SB | Tel'noi and Rabinovich, 1977, 2 | Two other values for the enthalpy of sublimation have been reported: 26.70 ± 0.41 kcal/mol Balducci, Bardi, et al., 1977 and 23.0 kcal/mol Dillard and Kiser, 1969; MS |
23.0 | CC-SB | Dillard and Kiser, 1969 | Two other values for the enthalpy of sublimation have been reported: 26.70 ± 0.41 kcal/mol Balducci, Bardi, et al., 1977 and 28.39 ± 0.50 kcal/mol Tel'noi and Rabinovich, 1977, 2; MS |
23.1 | CC-SB | Dillard and Kiser, 1969 | Two other values for the enthalpy of sublimation have been reported: 24.00 ± 0.41 kcal/mol Balducci, Bardi, et al., 1977 and 25.10 ± 0.50 kcal/mol Kir'yanov, Tel'noi, et al., 1976; MS |
References
Go To: Top, Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
KISER, DILLARD, et al., 2009
KISER, ROBERT W.; DILLARD, JOHN G.; DUGGER, DONALD L.,
Mass Spectrometry of Inorganic Halides, 2009, 153-180, https://doi.org/10.1021/ba-1968-0072.ch012
. [all data]
Diogo, Minas da Piedade, et al., 2001
Diogo, Hermínio P.; Minas da Piedade, Manuel E.; Gonçalves, Jorge M.; Monte, Manuel J.S.; Ribeiro da Silva, Manuel A.V.,
Enthalpies of Sublimation of M(η5-C5H5)2Cl2 (M = Ti, Zr, Hf, V, Nb, W) Complexes,
Eur. J. Inorg. Chem., 2001, 2001, 1, 257-262, https://doi.org/10.1002/1099-0682(20011)2001:1<257::AID-EJIC257>3.0.CO;2-2
. [all data]
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A.,
Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2
. [all data]
Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B.,
Thermochemistry of organic compounds of transition metals,
Usp. Khim., 1977, 46, 8, 1337. [all data]
Tel'noi and Rabinovich, 1977, 2
Tel'noi, V.I.; Rabinovich, I.B.,
Russ. Chem. Rev., 1977, 46, 689. [all data]
Balducci, Bardi, et al., 1977
Balducci, G.; Bardi, G.; de Maria, G.; Gigli, R.,
VII All-Union Calorimetry Conference, Moscow, 1977. [all data]
Dillard and Kiser, 1969
Dillard, J.G.; Kiser, R.W.,
The formation of gaseous ions from dicyclopentadienyltitanium dichloride and dicyclopentadienylzirconium dichloride upon electron impact,
J. Organometal. Chem., 1969, 16, 265. [all data]
Kir'yanov, Tel'noi, et al., 1976
Kir'yanov, K.V.; Tel'noi, V.I.; Vasil'eva, G.A.; Rabinovich, I.B.,
Dokl. Akad. Nauk SSSR, 1976, 231, 1021. [all data]
Notes
Go To: Top, Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.), References
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ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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