Silicon dimer


Gas Phase Heat Capacity (Shomate Equation)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. - 1100.1100. - 6000.
A 24.1998847.92605
B 31.58280-4.345921
C -8.2623131.037265
D -3.875582-0.072474
E 0.150614-0.208383
F 581.9149571.7143
G 250.9182280.7259
H 589.9440589.9440
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in March, 1967 Data last reviewed in March, 1967
Temperature
(K)
Cp
(J/mol*K)

(J/mol*K)
-(G° - H°298.15)/T
(J/mol*K)
H° - H°298.15
(kJ/mol)
298.34.47229.8229.8-0.00
300.34.50230.0229.80.07
400.36.20240.2231.23.60
500.38.04248.4233.87.31
600.39.76255.5236.911.20
700.41.24261.8240.015.26
800.42.43267.4243.119.44
900.43.29272.4246.023.73
1000.43.80277.0248.928.09
1100.43.91281.2251.732.48
Temperature
(K)
Cp
(J/mol*K)

(J/mol*K)
-(G° - H°298.15)/T
(J/mol*K)
H° - H°298.15
(kJ/mol)
1100.44.13281.2251.732.48
1200.43.93285.0254.336.89
1300.43.75288.5256.841.27
1400.43.57291.8259.245.64
1500.43.40294.8261.449.98
1600.43.25297.6263.654.32
1700.43.11300.2265.758.63
1800.42.98302.6267.762.94
1900.42.86305.0269.667.23
2000.42.75307.2271.471.51
2100.42.66309.2273.275.78
2200.42.57311.2274.880.04
2300.42.50313.1276.584.30
2400.42.43314.9278.088.54
2500.42.38316.7279.592.78
2600.42.33318.3281.097.02
2700.42.30319.9282.4101.2
2800.42.27321.5283.8105.5
2900.42.25322.9285.1109.7
3000.42.24324.4286.4113.9
3100.42.24325.8287.6118.2
3200.42.25327.1288.9122.4
3300.42.26328.4290.0126.6
3400.42.27329.7291.2130.8
3500.42.30330.9292.3135.1
3600.42.33332.1293.4139.3
3700.42.36333.2294.4143.5
3800.42.40334.4295.5147.8
3900.42.44335.5296.5152.0
4000.42.49336.5297.5156.2
4100.42.54337.6298.4160.5
4200.42.59338.6299.4164.8
4300.42.64339.6300.3169.0
4400.42.70340.6301.2173.3
4500.42.76341.6302.1177.6
4600.42.82342.5303.0181.8
4700.42.88343.4303.8186.1
4800.42.94344.3304.7190.4
4900.43.00345.2305.5194.7
5000.43.06346.1306.3199.0
5100.43.12346.9307.1203.3
5200.43.18347.8307.8207.6
5300.43.23348.6308.6212.0
5400.43.29349.4309.4216.3
5500.43.34350.2310.1220.6
5600.43.38351.0310.8225.0
5700.43.43351.7311.5229.3
5800.43.47352.5312.2233.6
5900.43.50353.2312.9238.0
6000.43.53354.0313.6242.3

References

Go To: Top, Gas Phase Heat Capacity (Shomate Equation), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]


Notes

Go To: Top, Gas Phase Heat Capacity (Shomate Equation), References