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Antimony tetramer

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
<1.00 ± 0.10LPESPolak, Gerber, et al., 1992Vertical Detachment Energy: 1.57±0.05 eV.; B

Ionization energy determinations

IE (eV) Method Reference Comment
7.40 ± 0.10PEElbel, Kudnig, et al., 1984LBLHLM
7.8EIBusse and Weil, 1982LBLHLM
8.4 ± 0.3EIKordis and Gingerich, 1973LLK
7.70 ± 0.06EICabaud, Hoareau, et al., 1973LLK
8.3 ± 0.3EIKohl, Prusaczyk, et al., 1967RDSH
9.1 ± 0.3EIGutbier, 1961RDSH
7.7 ± 0.3EIDeMaria, Drowart, et al., 1959RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Sb+15.0Sb3EIBusse and Weil, 1982LBLHLM
Sb+15. ± 0.5?EIDeMaria, Drowart, et al., 1959RDSH
Sb2+11.4Sb2EIBusse and Weil, 1982LBLHLM
Sb2+1.?EIDeMaria, Drowart, et al., 1959RDSH
Sb3+10.2SbEIBusse and Weil, 1982LBLHLM
Sb3+10.8 ± 0.3SbEIKordis and Gingerich, 1973LLK
Sb3+10.4 ± 0.3SbEIKohl, Prusaczyk, et al., 1967RDSH
Sb3+10.8 ± 0.3SbEIDeMaria, Drowart, et al., 1959RDSH


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Polak, Gerber, et al., 1992
Polak, M.L.; Gerber, G.; Ho, J.; Lineberger, W.C., Photoelectron Spectroscopy of Small Antimony Cluster Anions - Sb(-) Sb2(-), Sb3(-), and Sb4(-), J. Chem. Phys., 1992, 97, 12, 8990, https://doi.org/10.1063/1.463326 . [all data]

Elbel, Kudnig, et al., 1984
Elbel, S.; Kudnig, J.; Grodzicki, M.; Lempka, H.J., Photoelectron spectra of Group V compounds. The elements: Sb4, Chem. Phys. Lett., 1984, 109, 312. [all data]

Busse and Weil, 1982
Busse, B.; Weil, K.G., Mass spectrometric studies on the vapour phase composition over solid and fused Cs3Sb, Ber. Bunsen-Ges. Phys. Chem., 1982, 86, 93. [all data]

Kordis and Gingerich, 1973
Kordis, J.; Gingerich, K.A., Mass spectroscopic investigation of the equilibrium dissociation of gaseous Sb2, Sb3, Sb4, SbP, SbP3, and P2, J. Chem. Phys., 1973, 58, 5141. [all data]

Cabaud, Hoareau, et al., 1973
Cabaud, B.; Hoareau, A.; Nounou, P.; Uzan, R., High temperature mass spectrometric study of polyatomic antimony species by electron impact. Direct evidence for the existence of Sb3 molecules, Int. J. Mass Spectrom. Ion Phys., 1973, 11, 157. [all data]

Kohl, Prusaczyk, et al., 1967
Kohl, F.J.; Prusaczyk, J.E.; Carlson, K.D., New gaseous molecules of the pnictides, J. Am. Chem. Soc., 1967, 89, 5501. [all data]

Gutbier, 1961
Gutbier, H., Massenspektrometrische Untersuchungen der Verdampfungsvorgange bei einigen Verbindungen mit Zinkblende-Gitter im Temperaturbereich um 1000 degree K, Z. Naturforsch. A:, 1961, 16, 268. [all data]

DeMaria, Drowart, et al., 1959
DeMaria, G.; Drowart, J.; Inghram, M.G., Thermodynamic study of InSb with a mass spectrometer, J. Chem. Phys., 1959, 31, 1076. [all data]


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