Palladium dimer


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
1.6850 ± 0.0080LPESHo, Ervin, et al., 1991Singlet state 0.497±0.008 eV up; B
1.30 ± 0.15LPESGanteför, Gausa, et al., 1990EA: threshold, >=EA(adiabatic). Vertical Detachment Energy: 1.71±0.1 eV.; B

Ionization energy determinations

IE (eV) Method Reference Comment
7.7 ± 0.3EIGingerich, 1967RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ho, Ervin, et al., 1991
Ho, J.; Ervin, K.M.; Polak, M.L.; Gilles, M.K.; Lineberger, W.C., A Study of the Electronic Structures of Pd2- and Pd2 by Photoelectron Spectroscopy, J. Chem. Phys., 1991, 95, 7, 4845, https://doi.org/10.1063/1.461702 . [all data]

Ganteför, Gausa, et al., 1990
Ganteför, G.; Gausa, M.; Meiwes-Broer, K.-H.; Lutz, H.O., Photoelectron Spectroscopy of Silver and Palladium Cluster Anions, J. Chem. Soc. Farad. Trans., 1990, 86, 13, 2483, https://doi.org/10.1039/ft9908602483 . [all data]

Gingerich, 1967
Gingerich, K.A., On the equilibrium between monatomic and diatomic palladium and the appearance potential of Pd, Naturwiss., 1967, 54, 43. [all data]


Notes

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