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Ozone anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

O3- + Nitrogen = (O3- bullet Nitrogen)

By formula: O3- + N2 = (O3- bullet N2)

Quantity Value Units Method Reference Comment
Deltar2.70 ± 0.20kcal/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar18.4cal/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar-2.80 ± 0.50kcal/molTDAsHiraoka, 1988gas phase; B

O3- + Oxygen = (O3- bullet Oxygen)

By formula: O3- + O2 = (O3- bullet O2)

Quantity Value Units Method Reference Comment
Deltar2.10 ± 0.20kcal/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.0cal/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar-3.60 ± 0.50kcal/molTDAsHiraoka, 1988gas phase; B

(O3- bullet 4Oxygen) + Oxygen = (O3- bullet 5Oxygen)

By formula: (O3- bullet 4O2) + O2 = (O3- bullet 5O2)

Quantity Value Units Method Reference Comment
Deltar1.54kcal/molPHPMSHiraoka, 1988gas phase; «DELTA»rH, «DELTA»rS approximate; M
Quantity Value Units Method Reference Comment
Deltar16.4cal/mol*KPHPMSHiraoka, 1988gas phase; «DELTA»rH, «DELTA»rS approximate; M

(O3- bullet 2Nitrogen) + Nitrogen = (O3- bullet 3Nitrogen)

By formula: (O3- bullet 2N2) + N2 = (O3- bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar2.5 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.7cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 2Oxygen) + Oxygen = (O3- bullet 3Oxygen)

By formula: (O3- bullet 2O2) + O2 = (O3- bullet 3O2)

Quantity Value Units Method Reference Comment
Deltar2.0 ± 0.3kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.0cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 3Nitrogen) + Nitrogen = (O3- bullet 4Nitrogen)

By formula: (O3- bullet 3N2) + N2 = (O3- bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar2.3 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.2cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 3Oxygen) + Oxygen = (O3- bullet 4Oxygen)

By formula: (O3- bullet 3O2) + O2 = (O3- bullet 4O2)

Quantity Value Units Method Reference Comment
Deltar1.6 ± 0.3kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar15.4cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 4Nitrogen) + Nitrogen = (O3- bullet 5Nitrogen)

By formula: (O3- bullet 4N2) + N2 = (O3- bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar2.1 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.7cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 5Nitrogen) + Nitrogen = (O3- bullet 6Nitrogen)

By formula: (O3- bullet 5N2) + N2 = (O3- bullet 6N2)

Quantity Value Units Method Reference Comment
Deltar2.0 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.0cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 6Nitrogen) + Nitrogen = (O3- bullet 7Nitrogen)

By formula: (O3- bullet 6N2) + N2 = (O3- bullet 7N2)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.2cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 7Nitrogen) + Nitrogen = (O3- bullet 8Nitrogen)

By formula: (O3- bullet 7N2) + N2 = (O3- bullet 8N2)

Quantity Value Units Method Reference Comment
Deltar1.7 ± 0.3kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar17.5cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 8Nitrogen) + Nitrogen = (O3- bullet 9Nitrogen)

By formula: (O3- bullet 8N2) + N2 = (O3- bullet 9N2)

Quantity Value Units Method Reference Comment
Deltar1.5 ± 0.4kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar16.9cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet Nitrogen) + Nitrogen = (O3- bullet 2Nitrogen)

By formula: (O3- bullet N2) + N2 = (O3- bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar2.6 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.6cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet Oxygen) + Oxygen = (O3- bullet 2Oxygen)

By formula: (O3- bullet O2) + O2 = (O3- bullet 2O2)

Quantity Value Units Method Reference Comment
Deltar2.0 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.4cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 2Water) + Water = (O3- bullet 3Water)

By formula: (O3- bullet 2H2O) + H2O = (O3- bullet 3H2O)

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.5296.FAFehsenfeld and Ferguson, 1974gas phase; M

(O3- bullet Water) + Water = (O3- bullet 2Water)

By formula: (O3- bullet H2O) + H2O = (O3- bullet 2H2O)

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.2296.FAFehsenfeld and Ferguson, 1974gas phase; M

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, 1988
Hiraoka, K., Determination of the Stabilities of O3-(N2)n, O3-(O2)n, and O4-(N2)n from Measurements of the Gas Phase Equilibria, Chem. Phys., 1988, 125, 2-3, 439, https://doi.org/10.1016/0301-0104(88)87096-4 . [all data]

Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E., Laboratory studies of negative ion reactions with atmospheric trace constituents, J. Chem. Phys., 1974, 61, 3181. [all data]


Notes

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